Effect of Use of Alkaline Waste Materials as a CO Sink on the Physical and Mechanical Performance of Eco-Blended Cement Mortars-Comparative Study.

This research paper provides new insights into the impact of accelerated mineralization of alkaline waste materials on the physical and mechanical behavior of low-carbon cement-based mortars. Standardized eco-cement mortars were prepared by replacing Portland cement with 7% and 20% proportions of three alkaline waste materials (white ladle furnace slag, biomass ash, and fine concrete waste fraction) that had been previously carbonated in a static reactor at predefined humidity and CO concentration. The mortars' physical (total/capillary water absorption, electrical resistivity) and mechanical properties (compressive strength up to 90 d of curing) were analyzed, and their microstructures were examined using mercury intrusion porosimetry and computed tomography. The results reveal that carbonated waste materials generate a greater heat of hydration and have a lower total and capillary water absorption capacity, while the electrical resistivity and compressive strength tests generally indicate that they behave similarly to mortars not containing carbonated minerals. Mercury intrusion porosimetry (microporosity) indicates an increase in total porosity, with no clear refinement versus non-carbonated materials, while computed tomography (macroporosity) reveals a refinement of the pore structure with a significant reduction in the number of larger pores (>0.09 mm) and intermediate pores (0.001-0.09 mm) when carbonated residues are incorporated that varies depending on waste material. The construction and demolition waste (CCDW-C) introduced the best physical and mechanical behavior. These studies confirm the possibility of recycling carbonated waste materials as low-carbon supplementary cementitious materials (SCMs).