Single-Atom Underpotential Deposition at Specific Sites of N-Doped Graphene for Hydrogen Evolution Reaction Electrocatalysis.

Single-atom catalysts (SACs) have the advantages of good active site uniformity, high atom utilization, and high catalytic activity. However, the study of its controllable synthesis still needs to be thoroughly investigated. In this paper, we deposited Cu SAs on nanoporous N-doped graphene by underpotential deposition and further obtained a Pt SAC by a galvanic process. Electrochemical and spectroscopic analyses showed that the pyridine-like N defect sites are the specific sites for the underpotential-deposited SAs. The obtained Pt SAC exhibits a good activity in a hydrogen evolution reaction with a turnover frequency of 25.1 s. This work reveals the specific sites of UPD of SAs on N-doped graphene and their potential applications in HERs, which provides a new idea for the design and synthesis of SACs.