Wang I-Ta, Chou Ta-Lei, Hsu Chih-En, Lei Zhujialei, Wang Li-Min, Lin Ping-Hui, Luo Chih-Wei, Chen Chun-Wei, Kuo Chia-Nung, Lue Chin Shan, Chen Cheng-Hsuan, Hsueh Hung-Chung, Chu Ming-Wen
Center for Condensed Matter Sciences, National Taiwan University, Taipei, 10617, Taiwan.
Center of Atomic Initiative for New Materials, National Taiwan University, Taipei, 10617, Taiwan.
Nat Commun. 2024 Oct 29;15(1):9345. doi: 10.1038/s41467-024-53653-z.
Charge density waves (CDWs) are pervasive orders in solids that usually enhance the effective mass (m*) and reduce the Fermi velocity ( ) of carriers. Here, we report on the inverse - a reduced m* and an enhanced correlated with the growth of the CDW order in CuTe with gapped, practically linearly dispersing bands - reminiscent of emergent CDW-gapped topological semimetals. Using momentum-dependent electron energy-loss spectroscopy (q-EELS), we simultaneously capture m* and of the CDW-related, practically linearly dispersing electrons by plasmon dispersions across the transition (335 K, T), with m* of 0.28 m (m, the electron rest mass) and of ~ 0.005c (c, the speed of light) at 300 K. With the growth of the CDW order-parameter strength toward 100 K, the electrons become lighter and move faster by ~ 20%. Thorough inspection below T unveils the essential role of the increasing opening of the CDW gap. CuTe is a rich platform for the exploration of CDW/correlation physics with q-EELS established as a useful probe for this type of physics.
电荷密度波(CDW)是固体中普遍存在的有序态,通常会增加载流子的有效质量(m*)并降低其费米速度( )。在此,我们报道了相反的情况——在具有带隙、近乎线性色散能带的碲化铜(CuTe)中,随着CDW有序态的增长,m减小而 增大,这让人联想到新兴的CDW带隙拓扑半金属。利用动量相关电子能量损失谱(q-EELS),我们通过等离子体激元色散在转变温度(335 K,T)范围内同时捕获了与CDW相关的、近乎线性色散电子的m和 ,在300 K时m*为0.28 m(m为电子静止质量), 约为0.005c(c为光速)。随着CDW序参量强度在降温至100 K过程中不断增大,电子质量变轻,速度加快约20%。在转变温度T以下进行的详细研究揭示了CDW能隙不断增大所起的关键作用。碲化铜是探索CDW/关联物理的丰富平台,q-EELS已成为研究这类物理的有效探针。