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碲化铜中不断增强的电荷密度波有序状态使电子变轻并加速。

The growing charge-density-wave order in CuTe lightens and speeds up electrons.

作者信息

Wang I-Ta, Chou Ta-Lei, Hsu Chih-En, Lei Zhujialei, Wang Li-Min, Lin Ping-Hui, Luo Chih-Wei, Chen Chun-Wei, Kuo Chia-Nung, Lue Chin Shan, Chen Cheng-Hsuan, Hsueh Hung-Chung, Chu Ming-Wen

机构信息

Center for Condensed Matter Sciences, National Taiwan University, Taipei, 10617, Taiwan.

Center of Atomic Initiative for New Materials, National Taiwan University, Taipei, 10617, Taiwan.

出版信息

Nat Commun. 2024 Oct 29;15(1):9345. doi: 10.1038/s41467-024-53653-z.

Abstract

Charge density waves (CDWs) are pervasive orders in solids that usually enhance the effective mass (m*) and reduce the Fermi velocity ( ) of carriers. Here, we report on the inverse - a reduced m* and an enhanced correlated with the growth of the CDW order in CuTe with gapped, practically linearly dispersing bands - reminiscent of emergent CDW-gapped topological semimetals. Using momentum-dependent electron energy-loss spectroscopy (q-EELS), we simultaneously capture m* and of the CDW-related, practically linearly dispersing electrons by plasmon dispersions across the transition (335 K, T), with m* of 0.28 m (m, the electron rest mass) and of ~ 0.005c (c, the speed of light) at 300 K. With the growth of the CDW order-parameter strength toward 100 K, the electrons become lighter and move faster by ~ 20%. Thorough inspection below T unveils the essential role of the increasing opening of the CDW gap. CuTe is a rich platform for the exploration of CDW/correlation physics with q-EELS established as a useful probe for this type of physics.

摘要

电荷密度波(CDW)是固体中普遍存在的有序态,通常会增加载流子的有效质量(m*)并降低其费米速度( )。在此,我们报道了相反的情况——在具有带隙、近乎线性色散能带的碲化铜(CuTe)中,随着CDW有序态的增长,m减小而 增大,这让人联想到新兴的CDW带隙拓扑半金属。利用动量相关电子能量损失谱(q-EELS),我们通过等离子体激元色散在转变温度(335 K,T)范围内同时捕获了与CDW相关的、近乎线性色散电子的m和 ,在300 K时m*为0.28 m(m为电子静止质量), 约为0.005c(c为光速)。随着CDW序参量强度在降温至100 K过程中不断增大,电子质量变轻,速度加快约20%。在转变温度T以下进行的详细研究揭示了CDW能隙不断增大所起的关键作用。碲化铜是探索CDW/关联物理的丰富平台,q-EELS已成为研究这类物理的有效探针。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/14d8/11522371/0b07a34034b1/41467_2024_53653_Fig1_HTML.jpg

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