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用于增强储能应用的MoS-碳基材料的合成与表征

Synthesis and characterization of MoS-carbon based materials for enhanced energy storage applications.

作者信息

Szkoda Mariusz, Ilnicka Anna, Trzciński Konrad, Zarach Zuzanna, Roda Daria, Nowak Andrzej P

机构信息

Faculty of Chemistry, Department of Chemistry and Technology of Functional Materials, Gdańsk University of Technology, Narutowicza 11/12, Gdańsk, 80-233, Poland.

Advanced Materials Center, Gdańsk University of Technology, Narutowicza 11/12, Gdańsk, 80-233, Poland.

出版信息

Sci Rep. 2024 Oct 30;14(1):26128. doi: 10.1038/s41598-024-77545-w.

Abstract

The article delves into the synthesis and characterization of MoS-carbon-based materials, holding promise for applications in supercapacitors and ion batteries. The synthesis process entails the preparation of MoS and its carbon hybrids through exfoliation, hydrothermal treatment, and subsequent pyrolysis. Various analytical techniques were employed to comprehensively examine the structural, compositional, and morphological properties of the resulting materials. The article explores the electrochemical performance of these electrode materials in supercapacitors and ion batteries (LiB, SiB, KiB). Electrochemical measurements were conducted in aqueous electrolyte for supercapacitors and various aprotic electrolytes for ion batteries. Results highlight the impact of the synthesis process on electrochemical performance, emphasizing factors such as capacitance, rate capability, and charge/discharge cycle performance. Hydrothermally treated MoS-carbon exhibited a specific capacitance of approximately 150 F g in supercapacitors, attributed to its high surface area and efficient charge storage mechanisms. Additionally, for Li-ion battery materials without hydrothermal treatment showed impressive capacity retention of around 88% after 500 charge-discharge cycles, starting with an initial specific capacity of about 920 mAh/g. Long-term stability was demonstrated in both supercapacitors and lithium-ion batteries, with minimal capacitance degradation even after extensive charge-discharge cycles. This research underscores the potential of MoS-based materials as effective energy storage solutions.

摘要

本文深入探讨了MoS基碳材料的合成与表征,这些材料在超级电容器和离子电池应用方面具有潜力。合成过程包括通过剥离、水热处理以及随后的热解来制备MoS及其碳杂化物。采用了各种分析技术来全面研究所得材料的结构、组成和形态特性。本文探讨了这些电极材料在超级电容器和离子电池(锂离子电池、硅基电池、钾离子电池)中的电化学性能。在用于超级电容器的水性电解质和用于离子电池的各种非质子电解质中进行了电化学测量。结果突出了合成过程对电化学性能的影响,强调了诸如电容、倍率性能和充放电循环性能等因素。水热处理的MoS基碳材料在超级电容器中表现出约150 F/g的比电容,这归因于其高表面积和高效的电荷存储机制。此外,未经水热处理的锂离子电池材料在500次充放电循环后表现出令人印象深刻的容量保持率,约为88%,初始比容量约为920 mAh/g。在超级电容器和锂离子电池中均展示了长期稳定性,即使经过大量充放电循环,电容降解也很小。这项研究强调了MoS基材料作为有效储能解决方案的潜力。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7d84/11525990/d7862d405fb1/41598_2024_77545_Fig1_HTML.jpg

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