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超越光致变色：触发二芳基乙烯开关的其他刺激因素。

Beyond Photochromism: Alternative Stimuli to Trigger Diarylethenes Switching.

作者信息

Ai Qi, Lan Kangjun, Li Lin, Liu Zugang, Hu Xiaoguang

机构信息

College of Optical and Electronic Technology, China Jiliang University, Hangzhou, 310018, China.

School of Materials Science and Engineering, Zhengzhou University, Zhengzhou, 450001, China.

出版信息

Adv Sci (Weinh). 2024 Dec;11(48):e2410524. doi: 10.1002/advs.202410524. Epub 2024 Nov 3.

DOI:10.1002/advs.202410524
PMID:39488786
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11672267/
Abstract

Diarylethenes (DAEs) are typical photochemically reversible type (P-type) photochromic materials with excellent thermal stability and high fatigue resistance and are widely exploited as photo-switches for various applications in molecular devices, data storage, photoresponsive materials, and bioimaging, etc. In recent years, there is an increasing number of reports using heat, acid, electrochemistry, etc. to drive the isomerization reaction of DAEs. The response to two or more different stimuli enables multi-functionality within a single DAE molecule, which would facilitate complex logic-gate operations, multimode data storage, and increased information density. Herein, the recent advances in DAE systems utilizing stimuli "beyond photo" to trigger the isomerization processes from three perspectives: acidochromism, thermochromism, and electrochromism are reviewed. Emphasis is placed on the molecule design strategies and the underlying mechanisms for cyclization and cycloreversion processes addressed by the alternative stimulus. Then the noticeable applications made in multi-stimuli responsive DAE systems are summarized. Additionally, the challenges and opportunities of DAE switches driven by stimuli "beyond photo" in the future are also discussed.

摘要

二芳基乙烯（DAEs）是典型的光化学可逆型（P型）光致变色材料，具有出色的热稳定性和高抗疲劳性，被广泛用作光开关，用于分子器件、数据存储、光响应材料和生物成像等各种应用中。近年来，越来越多的报道使用热、酸、电化学等方法来驱动DAEs的异构化反应。对两种或更多种不同刺激的响应使得单个DAE分子具有多功能性，这将有助于复杂的逻辑门操作、多模式数据存储和增加信息密度。在此，从酸致变色、热致变色和电致变色三个角度综述了利用“光之外”的刺激来触发异构化过程的DAE系统的最新进展。重点介绍了分子设计策略以及由替代刺激引发的环化和环反转过程的潜在机制。然后总结了在多刺激响应DAE系统中取得的显著应用。此外，还讨论了未来由“光之外”的刺激驱动的DAE开关所面临的挑战和机遇。

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