Synchronous photocatalytic benzimidazole formation and olefin reduction by magnetic separable visible-light-driven Pd-g-CN-Vanillin@γ-FeO-TiO Nanocomposite.

A visible light-responsive magnetically separable photocatalyst Pd-g-CN-Vanillin@γ-FeO-TiO is fabricated using vanillin as a natural junction under ultrasonic agitation. Structural, morphological, optical, thermal, and magnetic assessments of the as-prepared catalyst are carried out. The photocatalyst successfully drives the simultaneous benzimidazole formation, and olefin hydrogenation with high atom economy under blue LED light and mild conditions. The photocatalytic activity of Pd-g-CN-Vanillin@γ-FeO-TiO is significantly affected by the γ-FeO:TiO weight ratio. PL spectra revealed the effective separation of carriers in the fabricated catalyst promoting its photocatalytic activity. The action spectra using the apparent quantum efficiency (AQE) exhibited the maximum AQEs at 520 and 750 nm in which the highest performance for styrene hydrogenation is observed. The title magnetically separable heterogeneous photocatalyst provides high yields of products under perfectly safe visible light, produces low/zero waste, and avoids using an external high-pressure hydrogen gas source, harmful solvents, undesirable additives, and reducing agents rendering green conditions for chemical reactions.