利用镍的氧化潜力实现可持续的碳氢化合物官能化

Khazanov Thomas M, Mukherjee Anusree

Department of Chemistry and Chemical Biology, Cornell University, Ithaca, NY 14853, USA.

Department of Chemistry and Geosciences, Jacksonville State University, 700 Pelham Rd N, Jacksonville, AL 36265, USA.

Molecules. 2024 Nov 2;29(21):5188. doi: 10.3390/molecules29215188.

While the oxidative chemistry of transition metals such as iron and copper is a highly developed area of investigation, the study of similar chemistry with nickel is much younger. However, nickel offers rich coordination chemistry with oxygen and other oxidants and is a promising avenue of research for applications such as sustainable hydrocarbon functionalization. Herein, we summarize the progress made recently in nickel coordination chemistry relevant to hydrocarbon functionalization and offer our perspectives on open questions in the field.

虽然铁和铜等过渡金属的氧化化学是一个高度发达的研究领域，但对镍的类似化学性质的研究则要年轻得多。然而，镍与氧和其他氧化剂有着丰富的配位化学，是可持续烃类官能团化等应用的一个有前景的研究途径。在此，我们总结了最近在与烃类官能团化相关的镍配位化学方面取得的进展，并对该领域的未解决问题发表我们的看法。