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静电纺丝介孔二氧化硅包覆的 CsPbBr 蓝色纤维:合成与荧光性质

Static-spun mesoporous silica-coated CsPbBr blue fibres: synthesis and fluorescence properties.

作者信息

Li Shengnan, Yang Yanrui, Song Jiahao, Meng Xianglin, Bai Cuibing, Wei Biao, Ma Fei, Zhang Lin

机构信息

Department of Chemistry & Materials Engineering, Fuyang Normal University, Fuyang, 236037, China.

出版信息

Discov Nano. 2024 Nov 12;19(1):180. doi: 10.1186/s11671-024-04145-y.

DOI:10.1186/s11671-024-04145-y
PMID:39532826
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11557819/
Abstract

Due to their excellent properties, blue CsPbBr quantum dots show great promise for full-colour display and lighting applications. This study used acetonitrile, a polar solvent, to post-treat CsPbBr quantum dots, resulting in a blue shift to 453 nm. To enhance stability, these quantum dots were encapsulated within the pore structure of mesoporous silica. A flexible luminescent fiber material was prepared using poly (lactic acid) (PLA) as the substrate, demonstrating improved hydrophobicity and stable optical properties. The material exhibited a contact angle of 99.7° and maintained 82.2% of its fluorescence intensity after 30 days at room temperature. These findings highlight its significant potential for optical applications.

摘要

由于其优异的性能,蓝色CsPbBr量子点在全彩显示和照明应用方面展现出巨大潜力。本研究使用极性溶剂乙腈对CsPbBr量子点进行后处理,使其蓝移至453纳米。为提高稳定性,这些量子点被封装在介孔二氧化硅的孔结构内。以聚乳酸(PLA)为基材制备了一种柔性发光纤维材料,其疏水性得到改善,光学性能稳定。该材料的接触角为99.7°,在室温下放置30天后仍保持其荧光强度的82.2%。这些发现突出了其在光学应用方面的巨大潜力。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9431/11557819/17c8e8c3eb7c/11671_2024_4145_Fig6_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9431/11557819/ad2629d368ba/11671_2024_4145_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9431/11557819/92f6bf56b0ba/11671_2024_4145_Fig2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9431/11557819/2f9aa4658383/11671_2024_4145_Fig3_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9431/11557819/5d1f0f6d0cea/11671_2024_4145_Fig4_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9431/11557819/05a09872f32f/11671_2024_4145_Fig5_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9431/11557819/17c8e8c3eb7c/11671_2024_4145_Fig6_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9431/11557819/ad2629d368ba/11671_2024_4145_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9431/11557819/92f6bf56b0ba/11671_2024_4145_Fig2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9431/11557819/2f9aa4658383/11671_2024_4145_Fig3_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9431/11557819/5d1f0f6d0cea/11671_2024_4145_Fig4_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9431/11557819/05a09872f32f/11671_2024_4145_Fig5_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9431/11557819/17c8e8c3eb7c/11671_2024_4145_Fig6_HTML.jpg

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本文引用的文献

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Biotoxicity of Halide Perovskites in Mice.卤化物钙钛矿在小鼠体内的生物毒性。
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