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用于轻量化应用的扇叶棕榈花废料生成的纤维素填料增强PMC复合材料的合成与表征

Synthesis and characterization of Borassus flabellifer flower waste-generated cellulose fillers reinforced PMC composites for lightweight applications.

作者信息

Karthik Krishnasamy, Velumayil Ramesh, Perumal Sunesh Narayana, Venkatesan Elumalai Perumal, Reddy D Siva Krishna, Annakodi Vivek Anand, Alwetaishi Mamdooh, Prabhakar S

机构信息

Department of Mechanical Engineering, Vel Tech Rangarajan Dr.Sagunthala R&D Institute of Science and Technology, Chennai, Tamil Nadu, 600062, India.

Department of Mechanical Engineering, Rohini College of Engineering and Technology, Palkulam, Anjugramam, 629401, India.

出版信息

Sci Rep. 2024 Nov 18;14(1):28389. doi: 10.1038/s41598-024-78410-6.

Abstract

The development of eco-friendly materials is a challenging one in the research field. Natural fibers are more accessible, biodegradable, inexpensive, and less dense. They offer fewer health risks and are eco-friendly compared to synthetic fibers. Natural fiber-reinforced polymer composites are new, eco-friendly materials with excellent mechanical and practical applications. Adding biofillers to composites improves strength and will replace synthetic materials. Utilizing cellulose as a filler for a natural starch matrix is an effective way to reduce the environmental impact of non-biodegradable materials. This study covers the influence of natural Borassus flabellifer flower microcrystalline cellulose (BFF MCC) fillers on banana fiber-reinforced polymer matrix composites. Fourier-transform infrared spectroscopic peaks at 2357, 1730, and 1245 cm were absent. This indicates that the amorphous proportion of banana fiber mat/BFF MCC-reinforced hybrid composites decreased. At 1% BFF MCC, thermogravimetric examination revealed an increase in the peak temperature of maximum degradation (389.6 °C). The hybrid banana composite's tensile strength (31.36 ± 4.39 to 39.83 ± 3.07 MPa) and flexural strength (71.05 ± 2.66 to 82.4 ± 1.66 MPa) were also improved after adding 3% BFF MCC as filler material. The primary objective is to evaluate the suitability of fiber-reinforced hybrid polymers with natural fillers for future engineering applications such as automotive parts, construction materials, 3D printing, etc. In addition, this study investigated how the reinforcement of microcrystalline cellulose can result in a material with enhanced performance as well as its mechanical characteristics (XRD, FTIR, TGA, and SEM characterization).

摘要

在研究领域,开发环保材料是一项具有挑战性的工作。天然纤维更容易获取、可生物降解、价格低廉且密度较小。与合成纤维相比,它们带来的健康风险更少,且对环境友好。天然纤维增强聚合物复合材料是新型环保材料,具有出色的机械性能和实际应用价值。向复合材料中添加生物填料可提高强度,并将取代合成材料。利用纤维素作为天然淀粉基质的填料是减少不可生物降解材料对环境影响的有效方法。本研究涵盖了天然贝叶棕花微晶纤维素(BFF MCC)填料对香蕉纤维增强聚合物基复合材料的影响。傅里叶变换红外光谱在2357、1730和1245 cm处的峰消失了。这表明香蕉纤维毡/BFF MCC增强混杂复合材料的非晶比例降低。在1% BFF MCC时,热重分析显示最大降解峰值温度升高(389.6 °C)。添加3% BFF MCC作为填料后,混杂香蕉复合材料的拉伸强度(从31.36±4.39至39.83±3.07 MPa)和弯曲强度(从71.05±2.66至82.4±1.66 MPa)也得到了提高。主要目的是评估含有天然填料的纤维增强混杂聚合物在未来工程应用(如汽车零部件、建筑材料、3D打印等)中的适用性。此外,本研究还调查了微晶纤维素的增强作用如何使材料性能及其机械特性(XRD、FTIR、TGA和SEM表征)得到提升。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e819/11570649/124424b16e2d/41598_2024_78410_Fig1_HTML.jpg

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