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用于锂离子电池的轻质3D网状镀铜聚酰亚胺集流体

Lightweight 3D-net Copper-Plated Polyimide Current Collector for Lithium-Ion Batteries.

作者信息

Song Tingyu, Min Yonggang

机构信息

School of Materials and Energy, Guangdong University of Technology, Guangzhou, 510006, China.

出版信息

ChemistryOpen. 2025 Apr;14(4):e202400018. doi: 10.1002/open.202400018. Epub 2024 Nov 26.

Abstract

Current collector (CC) is an indispensable constituent in lithium-ion battery (LIB). It plays an important role in supporting electrode materials and conducting electrons between the electrode materials and the external circuit. However, the density of metal CC is high and it hinders the lightweight development of LIB. In this work, lightweight three-dimensional (3D) CC was designed and prepared via a facile electroless plating method. The 3D copper-plated polyimide CC has a low areal density. The 3D structure of Cu-PI CC 2 can facilitate Li transfer between electrode materials and electrolyte owing to electrolyte can permeate through electrode. Moreover, the lithium titanate anode assembled with the 3D copper-plated polyimide Cu-PI CC 2 exhibited enhanced cycling and rate performance.

摘要

集流体(CC)是锂离子电池(LIB)中不可或缺的组成部分。它在支撑电极材料以及在电极材料与外部电路之间传导电子方面发挥着重要作用。然而,金属集流体的密度较高,这阻碍了锂离子电池的轻量化发展。在这项工作中,通过一种简便的化学镀方法设计并制备了轻质三维(3D)集流体。三维镀铜聚酰亚胺集流体具有较低的面密度。由于电解质可以渗透通过电极,Cu-PI CC 2的三维结构能够促进电极材料与电解质之间的锂传输。此外,与三维镀铜聚酰亚胺Cu-PI CC 2组装的钛酸锂负极表现出增强的循环性能和倍率性能。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e52c/11973500/05bca480f04a/OPEN-14-e202400018-g005.jpg

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