Ramaremisa Gibbon, Erasmus Rudolph M, Tutu Hlanganani, Saad Dalia
School of Chemistry, Molecular Sciences Institute, University of the Witwatersrand, South Africa.
School of Physics and Microscopy and Microanalysis Unit, University of the Witwatersrand, Johannesburg, South Africa.
Environ Pollut. 2025 Jan 15;365:125388. doi: 10.1016/j.envpol.2024.125388. Epub 2024 Nov 26.
This study presents the first comprehensive assessment of microplastics (MPs) in alcoholic (AB) and non-alcohol (NAB) beverages in South Africa. Beverages in various packaging materials, specifically glass, aluminium, and polyethylene terephthalate (PET) were tested for MP content. The samples were filtered and digested, then stained with Rose Bengal dye to facilitate particle identification, followed by physical and chemical characterisation using stereomicroscopy and micro-Raman spectroscopy, respectively. Fibers were the prevalent shape observed in AB packaged in glass, as well as in NAB (PET), and NAB (Aluminium). The Aluminium samples also exhibited a high abundance of fragments. Multivariate principal component analysis and Pearson correlation coefficient matrix revealed positive correlations between fibers of size ranges 0.02-0.1 mm and 0.1-0.5 mm in NAB samples. While in AB samples, the ranges were observed to be 1-2 mm and 2-3 mm. Six polymers were identified, namely: polypropylene (PP), polyethylene (PE), polyurethane (PU), polyamide (PA), PET, and polybutylene terephthalate (PBT). This study offers a holistic appraisal of MPs in commercially sold beverages in South Africa. It establishes a framework for assessing the socioeconomic impacts of MPs, including their commercial, environmental, social, and sustainability implications.
本研究首次对南非酒精饮料(AB)和非酒精饮料(NAB)中的微塑料(MPs)进行了全面评估。对各种包装材料的饮料,特别是玻璃、铝和聚对苯二甲酸乙二酯(PET)包装的饮料进行了MP含量测试。样品经过过滤和消化,然后用孟加拉玫瑰红染料染色以方便颗粒识别,随后分别使用体视显微镜和显微拉曼光谱进行物理和化学表征。在玻璃包装的AB饮料以及NAB(PET)和NAB(铝)饮料中观察到纤维是普遍存在的形状。铝制样品中也呈现出大量的碎片。多变量主成分分析和皮尔逊相关系数矩阵显示,NAB样品中尺寸范围为0.02 - 0.1毫米和0.1 - 0.5毫米的纤维之间存在正相关。而在AB样品中,观察到的范围是1 - 2毫米和2 - 3毫米。鉴定出六种聚合物,即:聚丙烯(PP)、聚乙烯(PE)、聚氨酯(PU)、聚酰胺(PA)、PET和聚对苯二甲酸丁二醇酯(PBT)。本研究对南非商业销售饮料中的MPs进行了全面评估。它建立了一个评估MPs社会经济影响的框架,包括其商业、环境、社会和可持续性影响。