Hybrid Strategies for Enhancing the Multifunctionality of Smart Dynamic Molecular Crystal Materials.

Dynamic molecular crystals are an emerging class of smart engineering materials that possess unique ability to convert external energy into mechanical motion. Moreover, they have being considered as strong candidates for dynamic elements in applications such as flexible electronic devices, artificial muscles, sensors, and soft robots. However, the inherent defects of molecular crystals like brittleness, short-life and fatigue, have significantly impeded their practical applications. Inspired by the concept of "the whole is greater than the sum of its parts" in the field of biology, building stimuli-response composites materials can be regarded as one of the ways to break through the current limitations of dynamic molecular crystals. Moreover, the hybrid materials can exhibit new functionalities that cannot be achieved by a single object. In this review, the focus was placed on the analysis and discussion of various hybrid strategies and options, as well as the functionalities of hybrid dynamic molecular crystal materials and the important practical applications of composite materials, with the introduction of photomechanical molecular crystals and flexible molecular crystals as a starting point. Moreover, the efficiency, limitations, and advantages of different hybrid methods were compared and discussed. Furthermore, the promising perspectives of smart dynamic molecular crystal materials were also discussed and the potential directions for future work were suggested.