Jiang Jili, Luo Jiangshuai, Ding Ke, Tang Yan, Zhang Hong, Ye Lijuan, Pang Di, Li Honglin, Li Wanjun
Chongqing Key Laboratory of Photo-Electric Functional Materials and Laser Technology, College of Physics and Electronic Engineering, Chongqing Normal University, Chongqing, 401331, P. R. China.
Small. 2025 Mar;21(12):e2406447. doi: 10.1002/smll.202406447. Epub 2024 Dec 1.
Developing high-performance, broad-spectrum ultraviolet photodetectors (PDs) with uniform response is crucial for optoelectronic applications like spectral analysis, optoelectronic logic gates, and multispectral imaging. This study constructs n-n type β-GaO:Si/GaN:Si heterojunction PDs using thermal oxidation, combining the advantages of β-GaO:Si and GaN:Si for excellent broad-spectrum response (UV-A to UV-C). A proposed channel model for GaN:Si oxidation includes hole formation, vortex structure development, channel formation, and grain growth, providing a basis for understanding β-GaO:Si/GaN:Si heterojunction formation. Uniform Si doping in the β-GaO layer, achieved through thermal oxidation, reduces resistivity, enhances the collection of photogenerated carriers from the underlying GaN layer, and hence enhances broad-spectrum response performance. The devices exhibit outstanding uniformity and sensitivity across the UV-A to UV-C range, with a peak responsivity of 2.44 × 10 A W and a photocurrent-to-dark current ratio of 1.3 × 10. Applications include optoelectronic logic gates executing "OR gate" and "AND gate" logic operations with 254 and 365 nm UV light, and a single-pixel multispectral imaging system producing high-contrast, clear "CNU" images with 254, 295, and 365 nm UV light. This research advances the understanding of oxide heterojunction formation and offers a method for developing high-performance, uniformly responsive broad-spectrum UV photodetectors for optoelectronic applications.