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硼酸盐、铝酸盐：锂离子电池阴离子的比较

Borates . aluminates: comparing the anion for lithium-ion batteries.

作者信息

Ould Darren M C, Penrod Megan E, McConnell Jessica B, Zabara Mohammed A, Berge Astrid H, O'Keefe Christopher A, Bond Andrew D, Menkin Svetlana, Grey Clare P, Wright Dominic S

机构信息

Yusuf Hamied Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge, CB2 1EW, UK.

The Faraday Institution, Quad One, Harwell Science and Innovation Campus, Didcot, OX11 ORA, UK.

出版信息

Chem Commun (Camb). 2024 Dec 17;61(1):129-132. doi: 10.1039/d4cc04812a.

DOI:10.1039/d4cc04812a
PMID:39620373
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11609998/
Abstract

Lithium borate and aluminate salts bearing a hexafluoroisopropoxy ligand have been prepared and investigated for use in lithium-ion batteries and Cu‖Li cells. Lithium aluminate salts have poorer air tolerance but Li[Al(hfip)] resulted in superior battery cycling, with lower overpotentials for plating and stripping in Cu‖Li cells.

摘要

已制备出带有六氟异丙氧基配体的硼酸锂盐和铝酸盐，并对其在锂离子电池及铜||锂电池中的应用进行了研究。铝酸锂盐的耐空气性较差，但Li[Al(hfip)]在电池循环性能方面表现出色，在铜||锂电池中具有较低的电镀和脱镀过电位。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/859d/11609998/3a49e49463d4/d4cc04812a-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/859d/11609998/cfab6c3eeea9/d4cc04812a-s1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/859d/11609998/78589eec8dcd/d4cc04812a-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/859d/11609998/f92838747eb6/d4cc04812a-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/859d/11609998/ecfd91a74399/d4cc04812a-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/859d/11609998/3a49e49463d4/d4cc04812a-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/859d/11609998/cfab6c3eeea9/d4cc04812a-s1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/859d/11609998/78589eec8dcd/d4cc04812a-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/859d/11609998/f92838747eb6/d4cc04812a-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/859d/11609998/ecfd91a74399/d4cc04812a-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/859d/11609998/3a49e49463d4/d4cc04812a-f4.jpg

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本文引用的文献

1
A novel calcium fluorinated alkoxyaluminate salt as a next step towards Ca metal anode rechargeable batteries.一种新型的钙氟代烷氧基铝酸盐，作为迈向钙金属阳极可充电电池的下一步研究方向。
J Mater Chem A Mater. 2023 May 23;11(27):14738-14747. doi: 10.1039/d3ta02084c. eCollection 2023 Jul 11.
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On the Practical Applications of the Magnesium Fluorinated Alkoxyaluminate Electrolyte in Mg Battery Cells.氟化烷氧基铝酸镁电解质在镁电池中的实际应用
ACS Appl Mater Interfaces. 2022 Jun 15;14(23):26766-26774. doi: 10.1021/acsami.2c05141. Epub 2022 Jun 1.
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Sodium Borates: Expanding the Electrolyte Selection for Sodium-Ion Batteries.
硼酸钠：拓展钠离子电池的电解质选择范围
Angew Chem Int Ed Engl. 2022 Aug 8;61(32):e202202133. doi: 10.1002/anie.202202133. Epub 2022 May 3.
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Inhibiting Polysulfide Shuttle in Lithium-Sulfur Batteries through Low-Ion-Pairing Salts and a Triflamide Solvent.通过低离子配对盐和三氟酰胺溶剂抑制锂硫电池中的多硫化物穿梭。
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6
Na[B(hfip)4] (hfip = OC(H)(CF3)2): a weakly coordinating anion salt and its first application to prepare ionic liquids.四[六氟异丙醇合]硼酸铷（hfip = OC(H)(CF3)2）：一种弱配位阴离子盐及其在制备离子液体中的首次应用。
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Angew Chem Int Ed Engl. 2004 Apr 13;43(16):2066-90. doi: 10.1002/anie.200300620.
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Relative Lewis basicities of six AI(ORF)4- superweak anions and the structures of LiA.六种Al(ORF)₄⁻超弱阴离子的相对路易斯碱性及LiA的结构
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