Sun Peihan, Hu Xiangmin, Yuan Shuhao, Peng Yanyan, Xu Tingfa, Zhong Haizheng
MIIT Key Laboratory for Low-Dimensional Quantum Structure and Devices, School of Materials Science and Engineering, Beijing Institute of Technology, Beijing, 100081, China.
School of Optics and Photonics, Beijing Institute of Technology, Beijing, 100081, China.
Nanophotonics. 2024 May 22;13(18):3599-3607. doi: 10.1515/nanoph-2024-0112. eCollection 2024 Aug.
Miniature spectrometer is powerful tool for scientific research and industrial inspection. Here, we report the fabrication of graded perovskite filters with tunable bandgap and their application in constructing miniature spectrometer. The graded perovskite filters were fabricated using a Finkelstein reaction between formed halogen ion with a preformed MAPbX film. The graded bandgap of perovskite films can be well tunned from 400 to 750 nm by controlling the volume ratio between 5,5-dimethyl-1-pyrroline -oxide and benzyl chloride(bromide). By combining a deep residual network, graded bandgap perovskite film and commercial CMOS sensor chip, a miniature spectrometer is demonstrated, achieving an accurate spectrum reconstruction (PSNR = 40.749) with monochromatic spectral resolution of 1.31 nm.
微型光谱仪是科研和工业检测的强大工具。在此,我们报道了具有可调带隙的梯度钙钛矿滤光片的制备及其在构建微型光谱仪中的应用。梯度钙钛矿滤光片是通过已形成的卤素离子与预先形成的MAPbX薄膜之间的芬克尔斯坦反应制备的。通过控制5,5-二甲基-1-吡咯啉氧化物与苄基氯(溴)之间的体积比,钙钛矿薄膜的梯度带隙可以很好地从400纳米调谐到750纳米。通过结合深度残差网络、梯度带隙钙钛矿薄膜和商用CMOS传感器芯片,展示了一种微型光谱仪,实现了准确的光谱重建(PSNR = 40.749),单色光谱分辨率为1.31纳米。