通过多重键合协同作用构建的基于聚乙烯醇/壳聚糖的多功能水凝胶及其在柔性传感器中的应用。

PVA/chitosan-based multifunctional hydrogels constructed through multi-bonding synergies and their application in flexible sensors.

作者信息

Wang Tiantian, Xu Bingbing, Yu Tong, Yu Yan, Fu Jiayi, Wang Yuhang, Gao Xianwu, Xue Zhebin, Li Ruoxin, Chang Guangtao

机构信息

College of Textile and Clothing Engineering, Soochow University, Suzhou 215123, China.

College of Textiles and garment, Liaodong University, Dandong 118003, China.

出版信息

Carbohydr Polym. 2025 Feb 15;350:123034. doi: 10.1016/j.carbpol.2024.123034. Epub 2024 Nov 17.

Abstract

Hydrogels have garnered significant interest as promising materials for flexible wearable devices. However, it remains a major challenge to develop multifunctional hydrogels. In this study, we prepared a multifunctional hydrogel based on the polyvinyl alcohol (PVA) and chitosan (CS), which is characterized by high strength, good electrical conductivity, and resistance to freezing and water retention. The hydrogel formulation utilizes p-carboxyphenylboronic acid (PBA) and MXene in combination with freeze-thaw cycling and glycerin (GL) immersion technology. Additionally, we explored the applications of this hydrogel in motion detection and sensing. Research results indicate that the hydrogel has excellent mechanical properties, achieving a strength of up to 3.42 MPa, with modulus and toughness improved by 7 times and 5 times, respectively, compared to pure PVA hydrogels. Moreover, when the MXene dispersion is at 8 vol%, the conductivity is 163.15 mS/m, and we explore their applications in strain sensing (GF = 7.03) and motion detection. The hydrogels exhibit a good strain range (600 %) and a fast response time (42 ms), as well as regular and stable electrical signals demonstrated at joints and breathing, providing strategic support for the application of this hydrogel in the field of smart wearable flexibility.

摘要

水凝胶作为用于柔性可穿戴设备的有前景的材料已引起了极大的关注。然而,开发多功能水凝胶仍然是一项重大挑战。在本研究中,我们制备了一种基于聚乙烯醇(PVA)和壳聚糖(CS)的多功能水凝胶,其特点是强度高、导电性好、抗冻且保水。该水凝胶配方利用对羧基苯硼酸(PBA)和MXene,并结合冻融循环和甘油(GL)浸渍技术。此外,我们探索了这种水凝胶在运动检测和传感方面的应用。研究结果表明,该水凝胶具有优异的机械性能,强度高达3.42MPa,与纯PVA水凝胶相比,模量和韧性分别提高了7倍和5倍。此外,当MXene分散体含量为8体积%时,电导率为163.15mS/m,我们还探索了它们在应变传感(GF = 7.03)和运动检测中的应用。该水凝胶表现出良好的应变范围(600%)和快速响应时间(42ms),并且在关节和呼吸时展示出规则且稳定的电信号,为这种水凝胶在智能可穿戴柔性领域的应用提供了策略支持。

文献AI研究员

20分钟写一篇综述,助力文献阅读效率提升50倍

立即体验

用中文搜PubMed

大模型驱动的PubMed中文搜索引擎

马上搜索