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一种在低床层温度下激光烧结聚合物粉末的新加工方法。

A New Processing Method for Laser Sintering Polymer Powders at Low Bed Temperatures.

作者信息

Yang Lanti, Gu Hao, Bashir Zahir

机构信息

SABIC Analytical Science Europe, Corporate T&I, Plasticslaan 1, 4612 PX Bergen op Zoom, The Netherlands.

SABIC Global Application Technology Europe, Specialties, Plasticslaan 1, 4612 PX Bergen op Zoom, The Netherlands.

出版信息

Polymers (Basel). 2024 Nov 26;16(23):3301. doi: 10.3390/polym16233301.

Abstract

Most current laser sintering (LS) machines for polymer powders operate with a maximum bed temperature of 200 °C, limiting the use of higher melting polymers like polyethylene terephthalate (PET), which melts at ~250 °C. Using bed temperatures of ≤200 °C leads to severe part-distortion due to curl and warpage during the sintering process. The paper presents a processing method for LS at low bed temperatures, using an in situ printed anchor film to conquer curl and warpage. With the use of the anchor film, PET parts were successfully printed without machine stoppage at bed temperatures as low as 150 °C, which is about 80 °C lower than the bed temperature for a regular process for PET without the anchor film. The anchor film acts as a frictional restraint, effectively preventing the curling and warping during printing that typically result from crystallization-induced shrinkage at low bed temperatures. Whereas previous studies have employed 13 mm thick anchoring sheets bolted to the machine to prevent curl and warpage at low bed temperatures, our method uses a flexible in situ printed ~70 μm thick film to which the built part naturally adheres. The in situ printed film is easily detachable from the part after the build. The standard LS material, polyamide 12 (PA12), was also printed with lowered bed temperaturewhere the benefit would be reduced thermal degradation of the powder and decreased energy consumption during the sintering process.

摘要

目前,大多数用于聚合物粉末的激光烧结(LS)机器的最高床层温度为200°C,这限制了诸如聚对苯二甲酸乙二酯(PET)等高熔点聚合物的使用,PET的熔点约为250°C。在200°C及以下的床层温度下进行烧结,会因烧结过程中的卷曲和翘曲导致严重的零件变形。本文提出了一种在低床层温度下进行激光烧结的加工方法,即使用原位打印的锚固膜来克服卷曲和翘曲问题。通过使用锚固膜,在低至150°C的床层温度下成功打印出PET零件,且无需停机,这比不使用锚固膜的PET常规加工床层温度低约80°C。锚固膜起到摩擦约束作用,有效防止了在低床层温度下因结晶诱导收缩而导致的打印过程中的卷曲和翘曲。以往的研究采用13毫米厚的锚固板用螺栓固定在机器上,以防止低床层温度下的卷曲和翘曲,而我们的方法使用的是一种柔性的原位打印的约70微米厚的薄膜,成型零件会自然附着在该薄膜上。成型后,原位打印的薄膜很容易从零件上分离。标准的激光烧结材料聚酰胺12(PA12)也在较低的床层温度下进行了打印,这样做的好处是减少了粉末的热降解,并降低了烧结过程中的能耗。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5088/11644084/6aaa6dc99290/polymers-16-03301-g001.jpg

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