Rajan Kalavathy, Berton Paula, Rogers Robin D, Shamshina Julia L
Department of Plant and Soil Science, Fiber and Biopolymer Research Institute, Texas Tech University, Lubbock, TX 79409, USA.
Chemical and Petroleum Engineering Department, University of Calgary, Calgary, AB T2N 1N4, Canada.
Polymers (Basel). 2024 Dec 7;16(23):3438. doi: 10.3390/polym16233438.
By reflecting on the history and environmental impact of conventional biorefining, such as kraft pulping, we aim to explore important questions about how natural polymers can be more sustainably sourced to develop bio-products and reduce reliance on plastics. Since the Industrial Revolution, chemical pulping processes have enabled the mass production of cellulosic products from woody biomass. Kraft pulping, which dominates within modern pulp and paper mills, has significantly contributed to environmental pollution and carbon emissions due to sulfurous byproducts and its high water and energy consumption. While chemical pulping technologies have advanced over time, with improvements aimed at enhancing sustainability and economic feasibility, conventional biorefineries still face challenges related to biomass conversion efficiency and environmental impact. For example, efforts to fully utilize wood resources, such as isolating lignin from black liquor, have made limited progress. This perspective provides a thoughtful examination of the growth of chemical pulping, particularly the kraft process, in the production of consumer goods and its environmental consequences. It also presents key insights into the bottlenecks in developing truly sustainable biomass conversion technologies and explores potential alternatives to traditional chemical pulping.
通过反思传统生物炼制(如硫酸盐制浆)的历史和环境影响,我们旨在探讨一些重要问题,即如何更可持续地获取天然聚合物以开发生物产品并减少对塑料的依赖。自工业革命以来,化学制浆工艺已使从木质生物质大规模生产纤维素产品成为可能。在现代纸浆和造纸厂中占主导地位的硫酸盐制浆,由于含硫副产品及其高水耗和能耗,对环境污染和碳排放有显著贡献。虽然随着时间的推移化学制浆技术有所进步,改进旨在提高可持续性和经济可行性,但传统生物精炼厂仍面临与生物质转化效率和环境影响相关的挑战。例如,充分利用木材资源的努力,如从黑液中分离木质素,进展有限。这一观点对消费品生产中化学制浆尤其是硫酸盐制浆工艺的发展及其环境后果进行了深入审视。它还揭示了开发真正可持续的生物质转化技术的瓶颈,并探索了传统化学制浆的潜在替代方法。