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通过在波特兰水泥生产中用作矿物添加剂来高效管理石棉废物。

Efficient Management of Asbestos Waste Through Utilization as Mineral Additives in Portland Cement Production.

作者信息

Durczak Karol, Pyzalski Michał, Sujak Agnieszka, Juszczyk Michał, Sala Dariusz, Ustinovichius Leonas

机构信息

Department of Biosystems Engineering, Faculty of Environmental and Mechanical Engineering, Poznan University of Life Sciences, Wojska Polskiego 50, 60-627 Poznan, Poland.

Faculty of Materials Science and Ceramics, AGH University of Krakow, Al. Mickiewicza 30, 30-059 Krakow, Poland.

出版信息

Materials (Basel). 2024 Nov 26;17(23):5793. doi: 10.3390/ma17235793.

Abstract

This article presents research on the effectiveness of utilizing asbestos waste, particularly chrysotile asbestos, in the production of Portland cement. The study aimed to evaluate the feasibility of transforming asbestos cement (Eternit) through thermal treatment and its enrichment with mineral additives, enabling its integration into the clinker synthesis process. Differences in the physicochemical properties of types of cement produced from conventional raw materials and those manufactured using asbestos waste were analyzed. The research findings indicate that the presence of asbestos in cementitious materials leads to a significant mass loss of 29.4% due to thermal decomposition. Chemical analysis revealed the presence of aluminum oxide (AlO) and iron oxide (FeO) at levels of 4.10% and 3.54%, respectively, suggesting the formation of brownmillerite, a phase typical of cement clinker. Furthermore, compressive strength tests on asbestos-modified cements demonstrated comparable mechanical properties to reference cement (CEM I), indicating their potential applicability in construction. This study provides essential insights into the mineralogical composition of asbestos cement, which is crucial for developing effective methods for its safe disposal. It represents a significant step toward sustainable asbestos waste management and the promotion of innovative solutions in the construction industry.

摘要

本文介绍了关于利用石棉废料,特别是温石棉,生产波特兰水泥的有效性的研究。该研究旨在评估通过热处理和添加矿物添加剂来富集石棉水泥(埃特尼特),使其融入熟料合成过程的可行性。分析了由传统原材料生产的水泥类型与使用石棉废料制造的水泥的物理化学性质差异。研究结果表明,由于热分解,水泥材料中石棉的存在导致显著的29.4%的质量损失。化学分析显示,氧化铝(AlO)和氧化铁(FeO)的含量分别为4.10%和3.54%,这表明形成了棕色米勒石,这是水泥熟料的典型相。此外,对石棉改性水泥的抗压强度测试表明,其机械性能与参考水泥(CEM I)相当,表明它们在建筑中的潜在适用性。这项研究为石棉水泥的矿物组成提供了重要见解,这对于开发其安全处置的有效方法至关重要。它代表了朝着可持续石棉废料管理以及促进建筑业创新解决方案迈出的重要一步。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a7fd/11642541/69f5b69138f2/materials-17-05793-g001.jpg

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