Hsu Yu-Hsuan, Lin Shao-Hua, Wuu Dong-Sing, Horng Ray-Hua
Institute of Electronics, National Yang Ming Chiao Tung University, Hsinchu, 30010, Taiwan, ROC.
Department of Photonics, National Yang Ming Chiao Tung University, Hsinchu, 30010, Taiwan, ROC.
Discov Nano. 2024 Dec 18;19(1):209. doi: 10.1186/s11671-024-04169-4.
This study fabricated 10 μm chip size μLEDs of blue-light GaN based epilayers structure with different mesa processes using dry etching and ion implantation technology. Two ion sources, As and Ar, were applied to implant into the LED structure to achieve material isolation and avoid defects on the mesa sidewall caused by the plasma process. Excellent turn-on behavior was obtained in both ion-implanted samples, which also exhibited lower leakage current compared to the sample fabricated by the dry etching process. Additionally, lower dynamic resistance (R) and series resistance (R) were obtained with Ar implantation, leading to a better wall-plug efficiency of 10.66% in this sample. Consequently, outstanding external quantum efficiency (EQE) values were also present in both implant samples, particularly in the sample implanted with Ar ions. This study proves that reducing defects on the mesa sidewall can further enhance device properties by suppressing non-radiative recombination behavior in small chip size devices. Overall, if implantation is used to replace the traditional dry etching process for mesa fabrication, the ideality factor can decrease from 11.89 to 2.2, and EQE can improve from 8.67 to 11.03%.
本研究采用干法蚀刻和离子注入技术,通过不同的台面工艺制造了基于蓝光氮化镓外延层结构、芯片尺寸为10μm的μLED。使用砷(As)和氩(Ar)两种离子源对LED结构进行注入,以实现材料隔离,并避免等离子体工艺在台面侧壁上造成缺陷。两个离子注入样品均表现出优异的开启特性,与干法蚀刻工艺制造的样品相比,其漏电流也更低。此外,氩离子注入样品的动态电阻(R)和串联电阻(Rs)更低,该样品的壁插效率达到了10.66%,表现更佳。因此,两个离子注入样品均具有出色的外量子效率(EQE)值,尤其是氩离子注入样品。本研究证明,通过抑制小芯片尺寸器件中的非辐射复合行为,减少台面侧壁上的缺陷可以进一步提升器件性能。总体而言,如果采用注入工艺替代传统的干法蚀刻工艺来制造台面,理想因子可从11.89降至2.2,外量子效率可从8.67%提高至11.03%。