蛤壳废料和蛋壳废料中羟基磷灰石与商业合成羟基磷灰石的结构比较

Structural Comparison of Hydroxyapatite from Clam Shell Waste and Eggshell Waste Compared to Commercial Synthetic Hydroxyapatite.

作者信息

Idulhaq M, Mudigdo A, Utomo P, Wasita B, Trapsilantya M E

机构信息

Department of Orthopaedics and Traumatology, Universitas Sebelas Maret, Surakarta, Indonesia.

Department of Orthopaedics and Traumatology, Dr. Soeharso Orthopedic Hospital, Jawa Tengah, Indonesia.

出版信息

Malays Orthop J. 2024 Nov;18(3):27-31. doi: 10.5704/MOJ.2411.004.

Abstract

INTRODUCTION

This study compares the quality of hydroxyapatite in Anadara granosa waste and laying chicken eggshell waste to commercial synthetic hydroxyapatite.

MATERIAL AND METHODS

This experimental research included 27 samples of hydroxyapatite derived from clam shell waste (CSW-HAP), hydroxyapatite derived from eggshell waste (ESW-HAP), and commercial synthetic hydroxyapatite, with nine samples of each. The calcination method was used to process clam shell waste and eggshell waste into hydroxyapatite, which was then compared with synthetic hydroxyapatite from Bongros® for calcium and phosphate content. Scanning electron microscopy was used to compare their morphological structures.

RESULT

The mean calcium levels in the CW-HAP, EW-HAP, and control groups were 41.3±2.9%, 41.5±2.3%, and 39.6±5.0%, respectively. According to One Way ANOVA, there was no significant difference between the CW-HAP or EW-HAP groups and the control group (p=0.49). The mean phosphate levels in the CW-HAP, EW-HAP, and control groups were 8.1±1.2%, 8.1±1.3%, and 9.4±2.0%, respectively. The results were also not significant (p=0.146).

CONCLUSION

Clam shell waste and eggshells can be an alternative source of hydroxyapatite substitution, as demonstrated by the structural and porous formation of hydroxyapatite obtained from these sources (CW-HAP and EW-HAP) when compared to commercial synthetic hydroxyapatite.

摘要

引言

本研究比较了泥蚶废弃物和蛋鸡蛋壳废弃物中羟基磷灰石与商业合成羟基磷灰石的质量。

材料与方法

本实验研究包括27个羟基磷灰石样本,分别来自蛤壳废弃物(CSW-HAP)、蛋壳废弃物(ESW-HAP)和商业合成羟基磷灰石,每种各9个样本。采用煅烧法将蛤壳废弃物和蛋壳废弃物加工成羟基磷灰石,然后与Bongros®的合成羟基磷灰石比较钙和磷含量。使用扫描电子显微镜比较它们的形态结构。

结果

CW-HAP组、EW-HAP组和对照组的平均钙含量分别为41.3±2.9%、41.5±2.3%和39.6±5.0%。根据单因素方差分析,CW-HAP组或EW-HAP组与对照组之间无显著差异(p=0.49)。CW-HAP组、EW-HAP组和对照组的平均磷含量分别为8.1±1.2%、8.1±1.3%和9.4±2.0%。结果也无显著差异(p=0.146)。

结论

蛤壳废弃物和蛋壳可作为羟基磷灰石替代物的一种来源,与商业合成羟基磷灰石相比,从这些来源(CW-HAP和EW-HAP)获得的羟基磷灰石的结构和多孔形成证明了这一点。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5ee5/11647544/9e7ed8d84439/moj-18-027-f1.jpg

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