Wide-Bandgap Lead Halide Perovskites for Next-Generation Optoelectronics: Current Status and Future Prospects.

Over the past decade, lead halide perovskites (LHPs), an emerging class of organic-inorganic ionic-type semiconductors, have drawn worldwide attention, which injects vitality into next-generation optoelectronics. Facilely tunable bandgap is one of the fascinating features of LHPs, enabling them to be widely used in various nano/microscale applications. Notably, wide-bandgap (WBG) LHPs have been considered as promising alternatives to traditional WBG semiconductors owing to the merits of low-cost, solution processability, superior optoelectronic characteristics, and flexibility, which could improve the cost-effectiveness and expand the application scenarios of traditional WBG devices. Herein, we provide a comprehensive review on the up-to-date research progress of WBG LHPs and their optoelectronics in terms of material fundamentals, optoelectronic devices, and their practical applications. First, the features and shortcomings of WBG LHPs are introduced to objectively display their natural features. Then we separately depict three typical optoelectronic devices based on WBG LHPs, including solar cells, light emitting diodes, and photodetectors. Sequentially, the inspiring applications of these optoelectronic devices in integrated functional systems are elaborately demonstrated. At last, the remaining challenges and future promise of WBG LHPs in optoelectronic applications are discussed. This review highlights the significance of WGB LHPs for promoting the development of the next-generation optoelectronics industry.