The Preparation of High-Performance MoO Nanorods for 2.1 V Aqueous Asymmetric Supercapacitor.

In order to broaden the working voltage (1.23 V) of aqueous supercapacitors, a high-performance asymmetric supercapacitor with a working voltage window reaching up to 2.1 V is assembled using a nanorod-shaped molybdenum trioxide (MoO) negative electrode and an activated carbon (AC) positive electrode, as well as a sodium sulfate-ethylene glycol ((NaSO-EG) electrolyte. MoO electrode materials are fabricated by adjusting the hydrothermal temperature, hydrothermal time and solution's pH value. The specific capacity of the optimal MoO electrode material can reach as high as 244.35 F g at a current density of 0.5 A g. For the assembled MoO//AC asymmetric supercapacitor with a voltage window of 2.1 V, its specific capacity, the energy density, and the power density are 13.52 F g, 8.28 Wh kg, and 382.15 W kg at 0.5 A g, respectively. Moreover, after 5000 charge-discharge cycles, the capacity retention rate of the device still reaches 109.2%. This is mainly attributed to the small particle size of MoO nanorods, which can expose more electrochemically active sites, thus greatly facilitating the transport of electrolyte ions, immersion at the electrolyte/electrolyte interface and the occurrence of electrochemical reactions.