Song Xiaohui, Ye Yishen, Huang Shifeng, Han Xingguo, Huang Zhouping, Guan Wenfang, Yang Zhengwei, Wang Minggan
Key Laboratory of Special Engineering Equipment Design and Intelligent Driving Technology, Guilin University of Aerospace Technology, Guilin, 541004, China.
Liuzhou Hirotec Wuling Engineering Co., Ltd, Liuzhou, 545027, China.
Sci Rep. 2024 Dec 28;14(1):30858. doi: 10.1038/s41598-024-81699-y.
This paper purposed to prepare poly (lactic acid)/continuous cotton thread (PLA /CCT) filaments by using prepreg method, and investigated the properties of PLA/CCT filament and their 3D printed composites. Firstly, a prepreg device was home-made to immerse CCT with PLA melts. The effects of the dragging speed and tensioning equipment on the quality of PLA/CCT filament was investigated. The functions of the immersion temperature, diameter of CCT and alkali treatment of CCT to the tensile properties of PLA/CCT filament were inspected. The results showed that when the dragging speed was 12 r/min, the diameter of the PLA/CCT filament equaled to the standard 3D printed diameter (1.75 mm). Increasing the CCT diameter from 0.6 to 1.0 mm, the tensile strength was improved from 44.26 to 52.81 MPa. The alkali treatment reduced the contact angle of PLA dramatically, and further improved the interfacial compatibility between PLA and CCT, and enhanced the tensile properties of filament composites. Secondly, for achieving CCT without any cutting during the 3D printing, an un-cutting off route was planned. Taguchi experiment was used to investigate how the 3D printing processing parameters affect the flexural properties of the 3D printed PLA/CCT composites. Meanwhile, the impact properties of the 3D printed PLA/CCT composites were analyzed. The results showed that the flexural strength and strain of PLA were improved to 135 MPa and 4.39% with 3D parameters (210℃ of nozzle temperature and 6 mm/s of printing speed). The impact strength of PLA was enhanced dramatically by 5.5% times from 2.75 to 18.87 J/mm. Finally, a thermal experiment was carried out and the results showed that PLA did not degrade during the processing and its molecular structure stayed the same at various states. The results of this paper demonstrated that the natural fiber CCT can be used to enforce PLA and lower the cost of PLA, and the PLA/CCT composites have the potential to be applied in fields of 3D printing of light-weight parts.
本文旨在采用预浸法制备聚乳酸/连续棉线(PLA/CCT)长丝,并研究PLA/CCT长丝及其3D打印复合材料的性能。首先,自制了一台预浸设备,用PLA熔体浸渍棉线。研究了牵引速度和张紧设备对PLA/CCT长丝质量的影响。考察了浸渍温度、棉线直径和棉线碱处理对PLA/CCT长丝拉伸性能的作用。结果表明,当牵引速度为12 r/min时,PLA/CCT长丝的直径等于标准3D打印直径(1.75 mm)。将棉线直径从0.6 mm增加到1.0 mm,拉伸强度从44.26 MPa提高到52.81 MPa。碱处理显著降低了PLA的接触角,进一步改善了PLA与棉线之间的界面相容性,并提高了长丝复合材料的拉伸性能。其次,为了在3D打印过程中不切割棉线,规划了一条不切断路径。采用田口实验研究了3D打印工艺参数对3D打印PLA/CCT复合材料弯曲性能的影响。同时,分析了3D打印PLA/CCT复合材料的冲击性能。结果表明,在3D参数(喷嘴温度210℃,打印速度6 mm/s)下,PLA的弯曲强度和应变分别提高到135 MPa和4.39%。PLA的冲击强度从2.75 J/mm显著提高了5.5倍,达到18.87 J/mm。最后,进行了热实验,结果表明PLA在加工过程中没有降解,其分子结构在不同状态下保持不变。本文结果表明,天然纤维棉线可用于增强PLA并降低PLA成本,PLA/CCT复合材料具有应用于轻质部件3D打印领域的潜力。