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不同加载速率下改性磷石膏力学性能的试验研究

Experimental study on the mechanical properties of modified phosphogypsum at different loading rates.

作者信息

Zhang Bo, Xu Chaohua, Wu Qin, Qin Xiaohui, Wei Jiagang, Lu Zhen

机构信息

School of Civil Engineering and Architecture, Guizhou Minzu University, Guiyang, 550025, China.

Key Laboratory of Karst Environmental Geological Hazard Prevention, State Ethnic Affairs Commission, Guiyang, 550025, China.

出版信息

Sci Rep. 2024 Dec 30;14(1):32025. doi: 10.1038/s41598-024-83759-9.

Abstract

Phosphogypsum is the main industrial solid waste from wet process phosphoric acid production, which has significant potential for environmental sustainability and engineering applications when modified. In order to explore the mechanical properties of modified phosphogypsum (MG) in different loading environments, uniaxial compression tests were conducted at four loading rates: 0.03, 0.06, 0.12, and 0.6 mm/min. The test results show that MG undergoes creeping at the loading rate of 0.03 mm/min, quasi-static loading at 0.12 to 0.6 mm/min, and transition between the two states at 0.06 mm/min. As the loading rate increases, the crack initiation stress [Formula: see text], damage stress [Formula: see text], and peak strength [Formula: see text] gradually increase, but the increasing amplitude gradually decreases. Under quasi-static loading at 0.12 to 0.6 mm/min, [Formula: see text] and [Formula: see text] show no significant changes and remain at 0.52 and 0.81, respectively, close to the values of rock materials. As the loading rate increases from creep loading to quasi-static loading, the elastic strain energy increases slowly and steadily, while the total strain energy and dissipative strain energy decrease first and then increase slowly. With the axial stress increasing from 0 to 0.81[Formula: see text], the principal strain field changes from relatively uniform to a concentration band, which has a very steep angle with the horizontal direction. The research results provide an important theoretical basis for the engineering application of MG as building materials.

摘要

磷石膏是湿法磷酸生产过程中产生的主要工业固体废弃物,经过改性后在环境可持续性和工程应用方面具有巨大潜力。为了探究不同加载环境下改性磷石膏(MG)的力学性能,分别以0.03、0.06、0.12和0.6毫米/分钟这四种加载速率进行了单轴压缩试验。试验结果表明,MG在0.03毫米/分钟的加载速率下会发生蠕变,在0.12至0.6毫米/分钟时为准静态加载,而在0.06毫米/分钟时则处于两种状态的过渡阶段。随着加载速率的增加,裂纹起裂应力[公式:见原文]、损伤应力[公式:见原文]和峰值强度[公式:见原文]逐渐增大,但增大幅度逐渐减小。在0.12至0.6毫米/分钟的准静态加载下,[公式:见原文]和[公式:见原文]无显著变化,分别保持在0.52和0.81,接近岩石材料的值。随着加载速率从蠕变加载增加到准静态加载,弹性应变能缓慢且稳定地增加,而总应变能和耗散应变能则先减小后缓慢增加。随着轴向应力从0增加到0.81[公式:见原文],主应变场从相对均匀变为一个与水平方向夹角非常陡峭的集中带。研究结果为MG作为建筑材料的工程应用提供了重要的理论依据。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1997/11685988/8bf862b11a7d/41598_2024_83759_Fig1_HTML.jpg

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