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不同化学抛光工艺制备的选择性激光熔化Ti6AL4V多孔支架的治疗效果评估及机制分析

Evaluation of Treatment Effect and Mechanism Analysis of Ti6AL4V Porous Scaffolds Prepared by Selective Laser Melting with Different Chemical Polishing Processes.

作者信息

Peng Wen, Cheng Cai, Hu Jinwang, Liu Yami, Li Minmin, Song Changhui, Shi Wenqing

机构信息

School of Electronics and Information Engineering, Guangdong Ocean University, Zhanjiang, China.

Foshan Orthopedic Implant (Stable) Engineering Technology Research Center, Foshan, China.

出版信息

3D Print Addit Manuf. 2024 Oct 22;11(5):1746-1757. doi: 10.1089/3dp.2023.0103. eCollection 2024 Oct.

Abstract

The large amount of unfused powder that remains on the surface of Ti6AL4V porous scaffolds prepared by selective laser melting technology is a common problem. Therefore, this article investigated the effects of three different chemical polishing processes on the surface state, pore structure, and mechanical properties of small pore size scaffold materials at different polishing times in the field of implantable medical devices. The results show that the overall treatment effect of the simple chemical polishing process is poor, the internal treatment depth of porous support is insufficient and uneven, and the overall mechanical properties of the sample with the same porosity are average. The outer structure during the electrochemical polishing process showed an obvious treatment effect. However, the internal treatment depth and uniformity were significantly lower compared with the simple chemical polishing process, and the overall mechanical properties of the sample with the same porosity were inferior. The overall treatment effect, depth, and uniformity of the inner and outer structure of the sample using a dynamic chemical polishing process were significantly optimized, and the overall mechanical properties of the sample with the same porosity were superior to the other two methods. Furthermore, the main reasons for the nonuniform treatment effect between the inner and outer layers during the chemical polishing of porous scaffolds were observed to be related to the restricted exchange of etchant caused by the complex internal structure of porous scaffolds and the gas generated by the chemical reaction.

摘要

采用选择性激光熔化技术制备的Ti6AL4V多孔支架表面残留大量未熔合粉末是一个常见问题。因此,本文在可植入医疗器械领域研究了三种不同化学抛光工艺在不同抛光时间对小孔径支架材料表面状态、孔隙结构和力学性能的影响。结果表明,单纯化学抛光工艺的整体处理效果较差,多孔载体内部处理深度不足且不均匀,相同孔隙率样品的整体力学性能一般。电化学抛光过程中外部结构呈现明显处理效果。然而,与单纯化学抛光工艺相比,其内部处理深度和均匀性显著降低,相同孔隙率样品的整体力学性能较差。采用动态化学抛光工艺的样品内外结构的整体处理效果、深度和均匀性均得到显著优化,相同孔隙率样品的整体力学性能优于其他两种方法。此外,观察到多孔支架化学抛光过程中内外层处理效果不均匀的主要原因与多孔支架复杂内部结构导致的蚀刻剂交换受限以及化学反应产生的气体有关。

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本文引用的文献

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