双共振光谱揭示了过渡态附近的结构和动力学。
Double resonance spectroscopy reveals structure and dynamics near transition states.
作者信息
Baraban Joshua H, Field Robert W
机构信息
Department of Chemistry, Ben-Gurion University of the Negev, Beer Sheva, Israel.
Department of Chemistry, Massachusetts Institute of Technology, Cambridge, MA, USA.
出版信息
Nat Commun. 2025 Jan 3;16(1):76. doi: 10.1038/s41467-024-55253-3.
Abstract
A shared ambition of molecular spectroscopy and molecular dynamics is to establish the truths of chemical intuition on solid physical bedrock. Experimental characterization of the transition state was thought unattainable, but modern techniques have begun to achieve the incredible.
摘要
分子光谱学和分子动力学的一个共同目标是在坚实的物理基础上确立化学直觉的真理。过渡态的实验表征曾被认为是无法实现的，但现代技术已开始取得令人难以置信的成果。
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