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用于高性能超级电容器的无粘结剂泡沫镍上的g-CN修饰花状CuCoO阵列

g-CN modified flower-like CuCoO array on nickel foam without binder for high-performance supercapacitors.

作者信息

Ma Lina, He Xiaojie, He Shasha, Yu Shirui, Zhang Song, Fu Yongming

机构信息

Department of Food Science and Engineering, Moutai Institute Zunyi 564507 China.

School of Physics and Electronic Engineering, State Key Laboratory of Quantum Optics and Quantum Optics Devices, Institute of Laser Spectroscopy, Shanxi University Taiyuan 030006 China

出版信息

RSC Adv. 2025 Jan 3;15(1):323-330. doi: 10.1039/d4ra07645a. eCollection 2025 Jan 2.

DOI:10.1039/d4ra07645a
PMID:39758920
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11698128/
Abstract

This study investigates the impact of integrating g-CN into CuCoO electrodes on electrochemical performance working as binder-free electrodes. Flower-like CuCoO nanostructures on nickel foam are decorated with few-layer g-CN using a secondary hydrothermal process. The hierarchical g-CN/CuCoO nanoflower electrode demonstrates a specific capacity of 247.5 mA h g at a current density of 1 A g, while maintaining a capacity of 87.0 mA h g at a heightened current density of 5 A g. Notably, this electrode exhibited remarkable durability, retaining 98% of its capacity after 1000 cycles. The g-CN/CuCoO heterostructure shows promise for high-performance energy storage devices.

摘要

本研究调查了将g-CN集成到CuCoO电极中对其作为无粘结剂电极的电化学性能的影响。采用二次水热法在泡沫镍上的花状CuCoO纳米结构上装饰了几层g-CN。分层的g-CN/CuCoO纳米花电极在电流密度为1 A g时的比容量为247.5 mA h g,而在电流密度提高到5 A g时仍保持87.0 mA h g的容量。值得注意的是,该电极表现出显著的耐久性,在1000次循环后仍保留其容量的98%。g-CN/CuCoO异质结构在高性能储能器件方面具有潜力。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9e9f/11698128/54c106bb29c8/d4ra07645a-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9e9f/11698128/96e18003ed75/d4ra07645a-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9e9f/11698128/d244094a3ab6/d4ra07645a-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9e9f/11698128/63f859e673d3/d4ra07645a-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9e9f/11698128/bd7b4922dc2e/d4ra07645a-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9e9f/11698128/54c106bb29c8/d4ra07645a-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9e9f/11698128/96e18003ed75/d4ra07645a-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9e9f/11698128/d244094a3ab6/d4ra07645a-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9e9f/11698128/63f859e673d3/d4ra07645a-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9e9f/11698128/bd7b4922dc2e/d4ra07645a-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9e9f/11698128/54c106bb29c8/d4ra07645a-f5.jpg

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本文引用的文献

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Layered CuMnO Crednerite: Mapping the Phase Stabilization Region via Precise Compositional Control for Optimum Supercapacitor Performance.层状铜锰矿:通过精确的成分控制绘制相稳定区域以实现最佳超级电容器性能
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Achieving Ultrahigh Capacity with Self-Assembled Ni(OH) Nanosheet-Decorated Hierarchical Flower-like MnCoO Nanoneedles as Advanced Electrodes of Battery-Supercapacitor Hybrid Devices.
通过自组装 Ni(OH)纳米片修饰的分级花状 MnCoO 纳米针实现超高容量,作为电池-超级电容器混合器件的先进电极。
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One-pot hydrothermal synthesis of Nitrogen-doped graphene as high-performance anode materials for lithium ion batteries.一锅水热法合成氮掺杂石墨烯作为锂离子电池的高性能阳极材料。
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