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决定含硅复合材料独特热阻和表面性质的因素。

Factors Determining Unique Thermal Resistance and Surface Properties of Silicone-Containing Composites.

作者信息

Zielecka Maria, Rabajczyk Anna

机构信息

Scientific and Research Centre for Fire Protection-National Research Institute, Nadwiślańska 213, 05-420 Józefów, Poland.

出版信息

Materials (Basel). 2024 Dec 13;17(24):6088. doi: 10.3390/ma17246088.

DOI:10.3390/ma17246088
PMID:39769688
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11680083/
Abstract

This review discusses the key factors influencing the exceptional thermal resistance and surface properties of silicone-containing composites. Silicone polymers, known for their excellent chemical and physical properties, are widely used in a number of innovative products. In order to make silicone composites suitable for innovative applications, it is essential to ensure that they have both very good thermal resistance and superhydrophobic properties. Identification of the key factors influencing these properties enables the use of these composites in coatings, electronics and photovoltaic panels. The discussion includes the role of organosilicon polymer structures and the incorporation of micro- and nanoadditives to enhance the performance of these materials. Different methods for the modification and production of silicone composites are analyzed, with an emphasis on achieving thermal stability and surface superhydrophobicity simultaneously. The review highlights the growing demand for silicone-based coatings due to technological advances and environmental concerns. Furthermore, the role of surface modification and hierarchical surface structures in achieving these unique properties is discussed, as well as the potential applications and challenges in the development of next-generation silicone-containing materials.

摘要

本综述讨论了影响含硅复合材料卓越耐热性和表面性能的关键因素。有机硅聚合物以其优异的化学和物理性能而闻名，广泛应用于许多创新产品中。为了使有机硅复合材料适用于创新应用，确保它们同时具有非常好的耐热性和超疏水性能至关重要。识别影响这些性能的关键因素能够使这些复合材料应用于涂料、电子和光伏面板中。讨论内容包括有机硅聚合物结构的作用以及添加微米和纳米添加剂以增强这些材料的性能。分析了有机硅复合材料的不同改性和生产方法，重点是同时实现热稳定性和表面超疏水性。该综述强调了由于技术进步和环境问题，对有机硅基涂料的需求不断增长。此外，还讨论了表面改性和分级表面结构在实现这些独特性能方面的作用，以及下一代含硅材料开发中的潜在应用和挑战。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ea87/11680083/268a1519fa36/materials-17-06088-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ea87/11680083/d4dfe14d7439/materials-17-06088-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ea87/11680083/e9942833cf78/materials-17-06088-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ea87/11680083/bc79943971c4/materials-17-06088-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ea87/11680083/ef73cdd25fed/materials-17-06088-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ea87/11680083/4a75aecd5a25/materials-17-06088-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ea87/11680083/ace667372ac5/materials-17-06088-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ea87/11680083/479ef7bcdebc/materials-17-06088-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ea87/11680083/268a1519fa36/materials-17-06088-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ea87/11680083/d4dfe14d7439/materials-17-06088-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ea87/11680083/e9942833cf78/materials-17-06088-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ea87/11680083/bc79943971c4/materials-17-06088-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ea87/11680083/ef73cdd25fed/materials-17-06088-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ea87/11680083/4a75aecd5a25/materials-17-06088-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ea87/11680083/ace667372ac5/materials-17-06088-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ea87/11680083/479ef7bcdebc/materials-17-06088-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ea87/11680083/268a1519fa36/materials-17-06088-g008.jpg

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Robust superhydrophobic silicone/epoxy functional coating with excellent chemical stability and self-cleaning ability.具有优异化学稳定性和自清洁能力的坚固超疏水有机硅/环氧树脂功能涂层。
Nanoscale. 2023 Nov 16;15(44):17793-17807. doi: 10.1039/d3nr04062c.
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Three-Dimensionally Printed Expandable Structural Electronics Via Multi-Material Printing Room-Temperature-Vulcanizing (RTV) Silicone/Silver Flake Composite and RTV.
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Polymers (Basel). 2023 Apr 23;15(9):2003. doi: 10.3390/polym15092003.
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