Seansukato Sirisak, Arthanareeswaran Gangasalam, Taweepreda Wirach
Polymer Science Program, Division of Physical Science, Faculty of Science, Prince of Songkla University, Hat-Yai 90110, Thailand.
Membrane Research Laboratory, Department of Chemical Engineering, National Institute of Technology, Tiruchirappalli 620 015, Tamil Nadu, India.
Polymers (Basel). 2024 Dec 19;16(24):3551. doi: 10.3390/polym16243551.
Water pollution is a major global issue, and antibiotic drugs released into aquatic environments by the pharmaceutical industry, such as ciprofloxacin, have negative consequences on both human health and the ecosystem. In this study, the performance of PVA as a polymer ligand for ciprofloxacin (CPFX) removal is evaluated through polymer-enhanced ultrafiltration using a novel composite PVC-ZnO membrane. The initial concentration of the ciprofloxacin solution, pH, ionic strength, ideal polymer concentration, duration, and maximum retention capacity were among the factors that were examined. In order to remove ciprofloxacin from water, PVA is utilized as a polymeric binding agent in a complex manufacturing process. In this instance, the PVC-ZnO membrane with 1.0 weight percent ZnO had a 96.77% ciprofloxacin clearance rate. PVA polymer has a high clearance rate of 99.98% in 1wt% of ZnO in this composite membrane when added to the ciprofloxacin solution. Fourier transform infrared spectroscopy (FTIR), energy dispersive X-ray spectroscopy (EDS), scanning electron microscopy (SEM), ultraviolet spectroscopy, and X-ray diffraction (XRD) were used to analyze the production and features of composite PVC-ZnO membranes. It is anticipated that this study's discussion will be crucial to the development of higher-quality membrane technologies that remove pharmaceutical active chemicals from wastewater in an environmentally responsible manner without endangering the ecosystem. This investigation showed that composite PVC-ZnO membranes were effective materials for efficient removal of ciprofloxacin (CPFX).
水污染是一个重大的全球性问题,制药行业排放到水生环境中的抗生素药物,如环丙沙星,对人类健康和生态系统都有负面影响。在本研究中,通过使用新型复合PVC-ZnO膜的聚合物增强超滤来评估聚乙烯醇(PVA)作为去除环丙沙星(CPFX)的聚合物配体的性能。研究考察了环丙沙星溶液的初始浓度、pH值、离子强度、理想聚合物浓度、持续时间和最大保留容量等因素。为了从水中去除环丙沙星,在复合制备过程中,PVA被用作聚合物结合剂。在这种情况下,含1.0重量百分比ZnO的PVC-ZnO膜对环丙沙星的清除率为96.77%。当添加到环丙沙星溶液中时,PVA聚合物在这种复合膜中1wt%的ZnO存在下具有99.98%的高清除率。利用傅里叶变换红外光谱(FTIR)、能量色散X射线光谱(EDS)、扫描电子显微镜(SEM)、紫外光谱和X射线衍射(XRD)来分析复合PVC-ZnO膜的制备和特性。预计本研究的讨论对于开发更高质量的膜技术至关重要,这些技术能够以对环境负责的方式从废水中去除药物活性化学物质而不危及生态系统。本研究表明,复合PVC-ZnO膜是高效去除环丙沙星(CPFX)的有效材料。