Lipska Karolina, Betlej Izabela, Rybak Katarzyna, Nowacka Małgorzata, Boruszewski Piotr
Department of Technology and Entrepreneurship in Wood Industry, Institute of Wood Sciences and Furniture, Warsaw University of Life Sciences-SGGW, 159 Nowoursynowska St., 02-776 Warsaw, Poland.
Department of Wood Science and Wood Protection, Institute of Wood Sciences and Furniture, Warsaw University of Life Sciences-SGGW, 159 Nowoursynowska St., 02-776 Warsaw, Poland.
Polymers (Basel). 2024 Dec 20;16(24):3557. doi: 10.3390/polym16243557.
This study investigates the properties of composites produced using post-consumer polypropylene (PP) reinforced with lignocellulosic fillers from (black cumin) and rapeseed pomace. Using agri-food by-products like pomace supports waste management efforts and reduces the demand for wood in wood-plastic composites. The composite production method combined extrusion and hot flat pressing. Mechanical tests showed a decrease in the tested parameters. Compared to the control variant, the MOE decreased by 26.4% (PP_R variant) and 46.9% (PP_N variant), and the MOR value decreased by 78.7% (PP_N) and 55.1% (PP_R). No significant differences in surface roughness parameters were observed. The composite with nigella particles demonstrated increased wettability. TGA tests showed reduced thermal stability compared to PP and differences between composite variants. The composites exhibited susceptibility to fungal overgrowth, which suggests potential biodegradability. The composites demonstrated complete overgrowth by inoculated fungi, reaching 100% coverage, while samples from PP known to be resistant to biological factors remained unaffected. Although the mechanical properties of the composites were degraded, the use of lignocellulosic fillers offers undeniable advantages, such as waste management of lignocellulosic and polypropylene byproducts, reduced wood demand, and the potential biodegradability of the obtained composites. However, there is a need for further optimization of manufacturing processes and material composition to enhance the material performance.
本研究调查了使用来自黑种草籽和菜籽粕的木质纤维素填料增强的消费后聚丙烯(PP)制备的复合材料的性能。使用诸如果渣等农业食品副产品有助于废物管理,并减少木塑复合材料中对木材的需求。复合材料的生产方法结合了挤出和热平板压制。力学测试表明测试参数有所下降。与对照变体相比,弹性模量(MOE)下降了26.4%(PP_R变体)和46.9%(PP_N变体),抗弯强度(MOR)值下降了78.7%(PP_N)和55.1%(PP_R)。未观察到表面粗糙度参数有显著差异。含有黑种草籽颗粒的复合材料表现出润湿性增加。热重分析(TGA)测试表明,与PP相比热稳定性降低,且复合材料变体之间存在差异。这些复合材料表现出易受真菌过度生长影响,这表明具有潜在的生物降解性。复合材料在接种真菌后出现完全覆盖生长,覆盖率达到100%,而已知对生物因素有抗性的PP样品未受影响。尽管复合材料的力学性能有所下降,但使用木质纤维素填料具有不可否认的优势,如木质纤维素和聚丙烯副产品的废物管理、减少木材需求以及所得复合材料潜在的生物降解性。然而,需要进一步优化制造工艺和材料组成以提高材料性能。