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爆轰纳米金刚石烟灰——一种结构可定制的石墨/纳米金刚石混合碳基材料

Detonation Nanodiamond Soot-A Structurally Tailorable Hybrid Graphite/Nanodiamond Carbon-Based Material.

作者信息

Kurkin Tikhon S, Lebedev Oleg V, Golubev Evgeny K, Gatin Andrey K, Nepomnyashchikh Victoria V, Dolmatov Valery Yu, Ozerin Alexander N

机构信息

Enikolopov Institute of Synthetic Polymer Materials Russian Academy of Sciences (ISPM RAS), Profsoyuznaya St. 70, 117393 Moscow, Russia.

Moscow Center for Advanced Studies, Kulakova Str. 20, 123592 Moscow, Russia.

出版信息

Nanomaterials (Basel). 2025 Jan 1;15(1):56. doi: 10.3390/nano15010056.

DOI:10.3390/nano15010056
PMID:39791814
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11722865/
Abstract

The results of a comprehensive investigation into the structure and properties of nanodiamond soot (NDS), obtained from the detonation of various explosive precursors (trinitrotoluene, a trinitrotoluene/hexogen mixture, and tetryl), are presented. The colloidal behavior of the NDS particles in different liquid media was studied. The results of the scanning electron microscopy, dynamic light scattering, zeta potential measurements, and laser diffraction analysis suggested a similarity in the morphology of the NDS particle aggregates and agglomerates. The phase composition of the NDS nanoparticles was studied using X-ray diffraction, Raman spectroscopy, electron diffraction, transmission electron microscopy, atomic force microscopy, and scanning tunneling microscopy. The NDS particles were found to comprise both diamond and graphite phases. The ratio of diamond to graphite phase content varied depending on the NDS explosive precursor, while the graphite phase content had a significant impact on the electrical conductivity of NDS. The study of the mechanical and tribological characteristics of polymer nanocomposites, modified with the selected NDS particles, indicated that NDS of various types can serve as a viable set of model nanofillers.

摘要

本文展示了对由各种爆炸前驱体（三硝基甲苯、三硝基甲苯/黑索今混合物和特屈儿）爆炸产生的纳米金刚石烟灰（NDS）的结构和性质进行全面研究的结果。研究了NDS颗粒在不同液体介质中的胶体行为。扫描电子显微镜、动态光散射、zeta电位测量和激光衍射分析的结果表明，NDS颗粒聚集体和团聚体的形态具有相似性。使用X射线衍射、拉曼光谱、电子衍射、透射电子显微镜、原子力显微镜和扫描隧道显微镜研究了NDS纳米颗粒的相组成。发现NDS颗粒同时包含金刚石相和石墨相。金刚石相与石墨相含量的比例因NDS爆炸前驱体而异，而石墨相含量对NDS的电导率有显著影响。对用选定的NDS颗粒改性的聚合物纳米复合材料的力学和摩擦学特性的研究表明，各种类型的NDS都可以作为一组可行的模型纳米填料。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/aa8d/11722865/f5b5de788a40/nanomaterials-15-00056-g014.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/aa8d/11722865/2dde5d278f07/nanomaterials-15-00056-g001a.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/aa8d/11722865/e0ba62005f61/nanomaterials-15-00056-g005a.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/aa8d/11722865/c796bc4eb256/nanomaterials-15-00056-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/aa8d/11722865/f20845f344ef/nanomaterials-15-00056-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/aa8d/11722865/83e4424d20ad/nanomaterials-15-00056-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/aa8d/11722865/162e8efd9fa1/nanomaterials-15-00056-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/aa8d/11722865/adde891c6466/nanomaterials-15-00056-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/aa8d/11722865/2659b858f217/nanomaterials-15-00056-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/aa8d/11722865/716bbd48242d/nanomaterials-15-00056-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/aa8d/11722865/406e1f0c7d4d/nanomaterials-15-00056-g013.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/aa8d/11722865/f5b5de788a40/nanomaterials-15-00056-g014.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/aa8d/11722865/2dde5d278f07/nanomaterials-15-00056-g001a.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/aa8d/11722865/4c7020c69419/nanomaterials-15-00056-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/aa8d/11722865/be283d46d698/nanomaterials-15-00056-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/aa8d/11722865/4cf1314c4c22/nanomaterials-15-00056-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/aa8d/11722865/e0ba62005f61/nanomaterials-15-00056-g005a.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/aa8d/11722865/c796bc4eb256/nanomaterials-15-00056-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/aa8d/11722865/f20845f344ef/nanomaterials-15-00056-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/aa8d/11722865/83e4424d20ad/nanomaterials-15-00056-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/aa8d/11722865/162e8efd9fa1/nanomaterials-15-00056-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/aa8d/11722865/adde891c6466/nanomaterials-15-00056-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/aa8d/11722865/2659b858f217/nanomaterials-15-00056-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/aa8d/11722865/716bbd48242d/nanomaterials-15-00056-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/aa8d/11722865/406e1f0c7d4d/nanomaterials-15-00056-g013.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/aa8d/11722865/f5b5de788a40/nanomaterials-15-00056-g014.jpg

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