Tribological Properties of Selected Ionic Liquids in Lubricated Friction Nodes.

This article compares the rheological and tribological properties of three ionic liquids: Tributyl(methyl)phosphonium dimethyl phosphate 97%-MFCD, 1-Butyl-3-methylimidazolium hexafluorophosphate 97%-BMIMPF6, and 1-Butyl-3-methylimidazolium tetrafluoroborate 98%-BMIMBF4. Their density and kinematic viscosity at 20 °C and 40 °C were investigated, and tribological tests were carried out at the same temperatures with ball-on-disc contact. The test materials were made of 100Cr6 steel. A scanning electron microscope was used to image the wear tracks, while an EDS analyzer was employed to determine the chemical composition at the points of wear on the samples. A confocal microscope was used to analyze the geometric structure of the samples before and after the tribological tests. The results of the tests indicated that an increase in temperature reduced the dynamic viscosity of all the ionic liquids tested. At the same time, an increase in the MFCD and BMIMBF4 ionic liquid density and a decrease in the density of the BMIMPF6 ionic liquid were observed. The BMIMPF6 ionic liquid used for this study provided the lowest value of linear wear at both temperatures, ambient and 40 °C. However, for the BMIMBF4 ionic liquid, significant wear was observed for the tested discs and balls, with corrosive pitting on their surfaces.