Herbal Waste from Filter-Tea Production as Eco-Friendly Ash for Sustainable Natural Rubber Composites.

Herbal dust, a waste byproduct from filter-tea production, was annealed to form ash that can be incorporated into natural rubber as an eco-friendly filler. Three types of herbal dust ash (HDA), green tea, hibiscus, and lemon balm, were added at two different contents, 2.5 and 5 phr, into the rubber compound, while the content of carbon black, as a filler, was maintained at 50 phr in all samples. The impact of HDA type and content on the rheological and mechanical properties of rubber products was evaluated. Rheological analysis showed that HDA samples exhibited slightly lower maximum torque values (around 11.6 dNm) than ash-free samples (13.53 dNm), yet maintained vulcanization effectiveness with minimal impact on torque or cure rate metrics. Mechanical testing found that samples with 2.5 phr of lemon balm ash achieved comparable properties to samples without added ash, while samples with added hibiscus preserved crosslinking density and hardness. The addition of HDA led to decreases in tensile strength, elongation at break, and hardness values, with slight changes suggesting its applicability in similar industrial contexts. The findings highlight HDAs potential as a cost-effective, sustainable filler for rubber production, contributing to circular economy practices by repurposing significant amounts of tea waste into high-quality rubber materials.