Jahromi Hamideh Samari, Abdollahi Mohsen, Mazaheri Azardokht, Mantaghi Soleyman, Rezaeian Amirhomayoon, Sadouni Ali, Naseri Hamidreza, Taheri Kiumars, Hashemipour Fariborz, Hamzavi Foad, Naseh Abdolsamad
Department of Environment and Biotechnology, Research Institute of Petroleum Industry (RIPI), Tehran, Iran.
Petro Farzan Apadana Company, Tehran, Iran.
Heliyon. 2024 Dec 11;11(1):e41148. doi: 10.1016/j.heliyon.2024.e41148. eCollection 2025 Jan 15.
The absence of a mercaptan compounds analyzer in natural gas pressure reduction stations (PRS) odorizer leads to inaccuracies in the injection dosage, often resulting in quantities beyond standard limits and consequently increasing odorant consumption. Insufficient odorant levels in natural gas can pose safety risks to consumers, as the gas may become odorless at the end of the pipeline. Therefore, accurate determination of the concentration of key odorant compounds in natural gas can reduce both costs and environmental risks. In this study, a hybrid UV-IR analyzer for detecting key odorant compounds was designed and developed. Initially, regional conditions were examined, and various natural gas and odorant samples were analyzed to identify compound percentages, which were then used to prepare calibration gas cylinders. Based on the results of simulated conditions, the analyzer's structure was designed, and technical specifications of components were determined. The analyzer consists of mechanical and optoelectronic units, connected via fiber optics. Subsequently, an optical cell was designed and manufactured, and the performance of the analyzer's components was evaluated in laboratory testing systems. This device can measure two key compounds, tert-butyl mercaptan and isopropyl mercaptan, separately, simultaneously, or in mixtures, making it comparable to an online gas chromatograph (GC). Installing this analyzer in PRSs enables precise adjustment of odorant injection dosages based on the analyzer's real-time results.
天然气减压站(PRS)加臭装置中缺少硫醇化合物分析仪,导致注入剂量不准确,常常造成超出标准限值的量,从而增加加臭剂消耗。天然气中加臭剂含量不足会给消费者带来安全风险,因为在管道末端气体可能变得无味。因此,准确测定天然气中关键加臭剂化合物的浓度可以降低成本和环境风险。在本研究中,设计并开发了一种用于检测关键加臭剂化合物的紫外 - 红外混合分析仪。最初,对区域条件进行了考察,并对各种天然气和加臭剂样品进行分析以确定化合物百分比,然后用于制备校准气瓶。根据模拟条件的结果,设计了分析仪的结构,并确定了各部件的技术规格。该分析仪由机械和光电单元组成,通过光纤连接。随后,设计并制造了一个光学池,并在实验室测试系统中评估了分析仪各部件的性能。该装置可以分别、同时或混合测量两种关键化合物,叔丁基硫醇和异丙基硫醇,使其性能可与在线气相色谱仪(GC)相媲美。在PRS中安装这种分析仪能够根据分析仪的实时结果精确调整加臭剂注入剂量。