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一种用于高性能摩擦纳米发电机(TENGs)的由聚六亚甲基胍盐酸盐制成的新型聚合物复合材料。

A novel polymer composite from polyhexamethylene guanidine hydrochloride for high performance triboelectric nanogenerators (TENGs).

作者信息

Tung Doan T, Tam Le T T, Duong Nguyen T T, Dung Hoang T, Dung Ngo T, Duc Nguyen A, Hong Phan N, Dung Nguyen T, Minh Phan N, Lu Le T

机构信息

Institute for Tropical Technology, Vietnam Academy of Science and Technology 18 Hoang Quoc Viet Hanoi Vietnam

Graduate University of Science and Technology, Vietnam Academy of Science and Technology 18 Hoang Quoc Viet Hanoi Vietnam

出版信息

RSC Adv. 2025 Jan 10;15(2):844-850. doi: 10.1039/d4ra07768g. eCollection 2025 Jan 9.

DOI:10.1039/d4ra07768g
PMID:39802473
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11718442/
Abstract

In this study, we report the successful fabrication of a novel antibacterial triboelectric nanogenerator (TENG) using a polymer composite film based on polyhexamethylene guanidine hydrochloride (PHMG). The composite materials, with optimised ingredient ratios, consist of PHMG, polyvinyl alcohol (PVA) and glutaraldehyde (GA) as a crosslinking agent (PHMG-GA-PVA). Utilising 3D printing, these composite materials were directly deposited on the conductive substrates and used as positive TENG electrodes. The obtained results show that the TENGs based on PHMG-GA-PVA exhibit high output efficiency, achieving peak-to-peak open-circuit voltage ( ) and short-circuit current ( ) values of 664.5 V and 116.8 μA, respectively, at a low operating frequency of 1 Hz with an actuation force of 10 N. The device retains approximately 98% of its initial output voltage value after 360 000 contact-release cycles.

摘要

在本研究中,我们报告了一种基于聚六亚甲基胍盐酸盐(PHMG)的聚合物复合膜成功制备出新型抗菌摩擦纳米发电机(TENG)。这些具有优化成分比例的复合材料由PHMG、聚乙烯醇(PVA)和作为交联剂的戊二醛(GA)组成(PHMG-GA-PVA)。利用3D打印技术,将这些复合材料直接沉积在导电基板上,并用作TENG的正电极。所得结果表明,基于PHMG-GA-PVA的TENG表现出高输出效率,在1 Hz的低工作频率和10 N的驱动力下,分别实现了664.5 V的峰峰值开路电压( )和116.8 μA的短路电流( )值。在360000次接触-释放循环后,该装置保留了其初始输出电压值的约98%。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a70d/11718442/7fca49ac8281/d4ra07768g-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a70d/11718442/ce7279be9181/d4ra07768g-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a70d/11718442/27ca0b33390d/d4ra07768g-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a70d/11718442/e428a3284267/d4ra07768g-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a70d/11718442/91d8298550a8/d4ra07768g-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a70d/11718442/e140f574789f/d4ra07768g-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a70d/11718442/7fca49ac8281/d4ra07768g-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a70d/11718442/ce7279be9181/d4ra07768g-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a70d/11718442/27ca0b33390d/d4ra07768g-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a70d/11718442/e428a3284267/d4ra07768g-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a70d/11718442/91d8298550a8/d4ra07768g-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a70d/11718442/e140f574789f/d4ra07768g-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a70d/11718442/7fca49ac8281/d4ra07768g-f6.jpg

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