Pan Jianhai, Sun Zhefei, Wu Xiaoyu, Liu Tongchao, Xing Yurui, Chen Jiawei, Xue Zhichen, Tang Dafu, Dong Xiaoli, Zhang Hongti, Liu Haodong, Wei Qiulong, Peng Dong-Liang, Amine Khalil, Zhang Qiaobao
State Key Laboratory of Physical Chemistry of Solid Surfaces, College of Materials, Xiamen University, Xiamen 361005, China.
Chemical Sciences and Engineering Division, Argonne National Laboratory, Lemont, Illinois 60439, United States.
J Am Chem Soc. 2025 Jan 29;147(4):3047-3061. doi: 10.1021/jacs.4c09824. Epub 2025 Jan 14.
Advancements in the development of fast-charging and long-lasting microstructured alloying anodes with high volumetric capacities are essential for enhancing the operational efficiency of sodium-ion batteries (SIBs). These anodes, however, face challenges such as declined cyclability and rate capability, primarily due to mechanical degradation reduced by significant volumetric changes (over 252%) and slow kinetics of sodium-ion storage. Herein, we introduce a novel anode design featuring densely packed bismuth (Bi) embedded within highly conductive carbon microspheres to overcome the aforementioned challenges. Remarkably, the high loading Bi anode within carbon microspheres with a high tap density of 2.59 g cm possesses significant mechanical strength exceeding 590 MPa and limits volume swelling of only 10.9% post-sodiation. This anode demonstrates a high volumetric capacity (908.3 mAh cm), ultrafast chargeability (200 A g, full charge/discharge in just 5.5 s), and outstanding cyclability over 12,000 cycles and maintains exceptional cycling stability even at -30 °C. The full cell paired with a NaV(PO) cathode retains over 80% capacity after 600 cycles at 36 C, demonstrating a remarkable rate capability of 126 C (full charge/discharge in 28.6 s). Our comprehensive experimental evaluations and chemo-mechanical simulations shed light on the mechanisms underpinning the anode's superior performance. This development marks a significant advancement in the design of durable and fast-charging anodes for high-performance SIBs.
