Optimizing Soil Stabilization with Chitosan: Investigating Acid Concentration, Temperature, and Long-Term Strength.

Civil and geotechnical researchers are searching for economical alternatives to replace traditional soil stabilizers such as cement, which have negative impacts on the environment. Chitosan biopolymer has shown its capacity to efficiently minimize soil erosion, reduce hydraulic conductivity, and adsorb heavy metals in soil that is contaminated. This research used unconfined compression strength (UCS) to investigate the impact of chitosan content, long-term strength assessment, acid concentration, and temperature on the improvement of soil strength. Static triaxial testing was employed to evaluate the shear strength of the treated soil. Overall, the goal was to identify the optimum values for the mentioned variables so that the highest potential for chitosan-treated soil can be obtained and applied in future research as well as large-scale applications in geotechnical engineering. The UCS results show that chitosan increased soil strength over time and at high temperatures. Depending on the soil type, a curing temperature between 45 to 65 °C can be considered optimal. Chitosan biopolymer is not soluble in water, and an acid solution is needed to dissolve the biopolymer. Different ranges of acid solution were investigated to find the appropriate amount. The strength of the treated soil increased when the acid concentration reached its optimal level, which is 0.5-1%. A detailed chemical model was developed to express how acid concentration and temperature affect the properties of the biopolymer-treated soil. The SEM examination findings demonstrate that chitosan efficiently covered the soil particles and filled the void spaces. The soil was strengthened by the formation of hydrogen bonds and electrostatic interactions with the soil particles.