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沸水浸泡对纳米黏土增强竹纤维和玻璃纤维环氧复合材料力学性能及耐久性的影响

Effect of boiling water soaking on the mechanical properties and durability of nanoclay-enhanced bamboo and glass fiber epoxy composites.

作者信息

Ahmad Syed Mansoor, Gowrishankar M C, Shettar Manjunath

机构信息

Department of Mechanical and Industrial Engineering, Manipal Institute of Technology, Manipal Academy of Higher Education, Manipal, 576104, India.

出版信息

Sci Rep. 2025 Jan 29;15(1):3605. doi: 10.1038/s41598-025-87912-w.

Abstract

Fiber-reinforced polymer composites are subjected to harsh environmental conditions over the course of their designed lifespan. Studying the aging process of fiber-reinforced polymer composites exposed to boiling water is critical for improving their durability. This study uses a hand lay-up technique to fabricate composites from glass fiber, bamboo fiber, nanoclay, and epoxy. Tensile and flexural tests are conducted following ASTM standards. The % of water uptake of the boiling water-soaked specimens is measured, and the performance of the dry composites is compared with those of boiling water-soaked composites. The results show that boiling water-soaking conditions have an adverse impact on all the composites. Boiling water-soaked epoxy samples show a reduction in tensile properties by 25 and 30% and flexural properties by 18 and 22% under processes 1 and 2 of boiling water soaking, respectively, compared to dry ones. Meanwhile, for fiber-reinforced composites, the tensile properties decrease by 19 and 27%, and the flexural properties decline by 12 and 20% under processes 1 and 2 of boiling soaking, respectively. However, incorporating nanoclay enhances the tensile and flexural properties of the epoxy and the composites by 5 to 7% and 10 to 12%, respectively. The water absorption rate and the impact of boiling water-soaking on composite strength decrease with the addition of nanoclay. Additionally, nanoclay reduces the percentage of reduction in tensile properties by 17 and 26% and in flexural properties by 11 and 18% under processes 1 and 2 of boiling soaking, respectively. SEM analysis of the fracture surfaces reveals the causes of specimen failure under tensile load, with distinct differences between dry and boiling water-soaked specimens.

摘要

在其设计使用寿命期间,纤维增强聚合物复合材料会受到恶劣的环境条件影响。研究纤维增强聚合物复合材料在沸水中的老化过程对于提高其耐久性至关重要。本研究采用手工铺层技术,用玻璃纤维、竹纤维、纳米黏土和环氧树脂制备复合材料。按照美国材料与试验协会(ASTM)标准进行拉伸和弯曲试验。测量沸水煮过的试样的吸水率,并将干燥复合材料的性能与沸水煮过的复合材料的性能进行比较。结果表明,沸水煮的条件对所有复合材料都有不利影响。与干燥的环氧样品相比,在沸水煮过程1和过程2中,沸水煮过的环氧样品的拉伸性能分别降低了25%和30%,弯曲性能分别降低了18%和22%。同时,对于纤维增强复合材料,在沸水煮过程1和过程2中,拉伸性能分别降低了19%和27%,弯曲性能分别降低了12%和20%。然而,加入纳米黏土分别使环氧树脂和复合材料的拉伸性能提高了5%至7%,弯曲性能提高了10%至12%。随着纳米黏土的加入,复合材料的吸水率以及沸水煮对复合材料强度的影响降低。此外,在沸水煮过程1和过程2中,纳米黏土分别使拉伸性能的降低百分比减少了17%和26%,弯曲性能的降低百分比减少了11%和18%。对断裂表面的扫描电子显微镜(SEM)分析揭示了拉伸载荷下试样失效的原因,干燥试样和沸水煮过的试样之间存在明显差异。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/beed/11775142/0bf7206b034e/41598_2025_87912_Fig1_HTML.jpg

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