Rafael de Oliveira Thomas, Carlos Luz Lisboa Antonio
School of Chemical Engineering, University of Campinas, Av. Albert Einstein 500, Campinas, SP, 13083-852, Brazil.
Heliyon. 2025 Jan 4;11(2):e41642. doi: 10.1016/j.heliyon.2025.e41642. eCollection 2025 Jan 30.
This work investigates the energy cane pyrolysis by process simulation in Aspen Plus, evaluating which variety maximizes bio-oil yield with further economics to evaluate process feasibility. Three cultivars were selected: two natural, and , and one, IACSP955000, generated by a breeding program. Firstly, 100 kg/h of wet biomass entered a stoichiometric reactor (RSTOIC) at 450 °C and 40 bar, generating biochar, bio-oil and gases. Secondly, a sensitivity analysis using CSTR determined its volume for an equivalent bio-oil yield. The economics involved two scenarios: 1) Two years payback and 10 years plant life; 2) 2.71 years payback and 20 years plant life. The produced the highest bio-oil yield. A 50 L CSTR produced bio-oil yield compared to the RSTOIC. The techno-economic results were: for the first scenario, bio-oil price of US$ 1.49/L and an internal rate of return (IRR) of 34 %; for the second, bio-oil price of US$ 1.15/L and an IRR of 16 %. The bio-oil price was 2.1 times higher than the international, suggesting either the employment of catalytic pyrolysis or energy integration to increase the bio-oil yield or to improve its quality.
本研究通过在Aspen Plus中进行过程模拟来探究能源甘蔗的热解过程,评估哪种品种能使生物油产量最大化,并进一步进行经济分析以评估工艺的可行性。选择了三个品种:两个天然品种 和 ,以及一个通过育种计划培育出的品种IACSP955000。首先,100千克/小时的湿生物质在450℃和40巴的条件下进入化学计量反应器(RSTOIC),生成生物炭、生物油和气体。其次,使用连续搅拌釜式反应器(CSTR)进行敏感性分析,确定其体积以获得等效的生物油产量。经济分析涉及两种情景:1)两年回收期和10年工厂寿命;2)2.71年回收期和20年工厂寿命。 品种产生的生物油产量最高。一个50升的CSTR与RSTOIC相比产生了生物油产量。技术经济结果如下:对于第一种情景,生物油价格为1.49美元/升,内部收益率(IRR)为34%;对于第二种情景,生物油价格为1.15美元/升,IRR为16%。生物油价格比国际价格高出2.1倍,这表明要么采用催化热解,要么进行能量整合以提高生物油产量或改善其质量。