Maes Stephan, Badi Nezha, Winne Johan M, Du Prez Filip E
Polymer Chemistry Research Group, Centre of Macromolecular Chemistry (CMaC), Department of Organic and Macromolecular Chemistry, Faculty of Sciences, Ghent University, Ghent, Belgium.
Laboratory of Organic Synthesis, Department of Organic and Macromolecular Chemistry, Faculty of Sciences, Ghent University, Ghent, Belgium.
Nat Rev Chem. 2025 Mar;9(3):144-158. doi: 10.1038/s41570-025-00686-7. Epub 2025 Jan 31.
Dynamic covalent chemistry (DCC) allows the development of thermally (re)processable and recyclable polymer networks, which is a highly attractive feature for new generations of thermoset materials. However, despite a surge in academic interest wherein soon almost any imaginable DCC platform may have been applied in a thermoset formulation, dynamic or reversible covalent polymer networks have so far found only few industrial applications. This Review provides a perspective on the main strategies for the application of DCC in the design and development of bulk thermoset materials, and it presents some of the key hurdles for their industrial implementation. The polymer design strategies and associated chemistries are viewed from the perspective of how 'close to market' their development pathway is, thus providing a roadmap to achieve high-volume breakthrough applications.
动态共价化学(DCC)能够开发出可热(再)加工和可回收的聚合物网络,这对新一代热固性材料来说是极具吸引力的特性。然而,尽管学术界兴趣高涨,几乎任何可想象的DCC平台可能很快都已应用于热固性配方中,但动态或可逆共价聚合物网络迄今为止仅在少数工业应用中有所发现。本综述对DCC在本体热固性材料设计与开发中的应用主要策略进行了展望,并提出了其工业应用的一些关键障碍。从聚合物设计策略及其相关化学的开发途径与市场的接近程度的角度进行审视,从而提供一条实现大规模突破性应用的路线图。