Shao Yu, Mallory Rachel C, Dugas Magdalene, Flanagan Claire, Ligon Charles, Burks Gabriel R
Chemical and Biomolecular Engineering, University of Notre Dame, Notre Dame, IN, USA.
Chemistry. 2025 Jul 11;31(39):e202501440. doi: 10.1002/chem.202501440. Epub 2025 Jun 25.
The last three decades have witnessed a paradigm shift in the polymer industry, driven by the urgent need for sustainable materials. Growing awareness of environmental sustainability, coupled with increasingly stringent chemical regulations, has catalyzed significant investments in sustainable polymer materials. While much of the focus has been on plastics, rubbery materials have received comparatively less attention. With mechanical and chemical recycling as the current primary mode for disposing rubber waste, prospects for a suitable pathway to minimize hazardous microplastics derived from these highly crosslinked polymers sources seem bleak. This article aims to envision a future where the pathway toward biodegradable rubber materials becomes a more realistic possibility. We delve into the challenges, advancements, and future perspectives of biodegradable rubbery materials, with a particular emphasis on exploring the potential of utilizing polysaccharides derived from biomass combined with synthetic elastomers - including the utilization of dynamic covalent bonding and supramolecular chemistry approaches. In addition to the discussion on scientific questions, we address complementary issues on STEM education to put forth a more comprehensive vision for sustainability relating to broader society.
在对可持续材料的迫切需求推动下,聚合物行业在过去三十年经历了范式转变。对环境可持续性的认识不断提高,再加上日益严格的化学法规,促使人们对可持续聚合物材料进行了大量投资。虽然大部分注意力都集中在塑料上,但橡胶材料受到的关注相对较少。由于机械回收和化学回收是目前处理橡胶废料的主要方式,减少源自这些高度交联聚合物来源的有害微塑料的合适途径前景似乎黯淡。本文旨在设想一个未来,使通往可生物降解橡胶材料的途径成为更现实的可能性。我们深入探讨可生物降解橡胶材料的挑战、进展和未来前景,特别强调探索利用源自生物质的多糖与合成弹性体相结合的潜力——包括利用动态共价键和超分子化学方法。除了对科学问题的讨论,我们还探讨了科学、技术、工程和数学(STEM)教育的相关问题,以提出一个与更广泛社会相关的可持续性的更全面愿景。