Zou Wanghui, Wu Chenhui, Zhao Wei
School of Physical and Electronic Sciences, Changsha University of Science and Technology, Changsha 410114, China.
Sensors (Basel). 2025 Jan 24;25(3):691. doi: 10.3390/s25030691.
This study investigates the humidity-sensing properties of two semiconductor metal oxide (SMO)-reduced graphene oxide (RGO) nanocomposites: TiO/RGO and α-FeO/RGO, at room temperature. Both nanocomposites are synthesized via hydrothermal methods and coated onto printed circuit board (PCB) interdigital electrodes to construct humidity sensors. The surface morphology and crystallographic structure of the materials are characterized using field emission scanning electron microscopy (FESEM) and X-ray diffraction (XRD). The sensors are tested across a humidity range of 11%RH to 97%RH, and the impedance is measured over a frequency range of 1 Hz to 1 MHz. The results show that both TiO/RGO and α-FeO/RGO exhibit favorable humidity-sensing performance at room temperature. The sensitivity and humidity hysteresis of TiO/RGO are 12.2 MΩ/%RH and 3.811%RH, respectively, while those of α-FeO/RGO are 0.826 MΩ/%RH and 8.229%RH. The response and recovery times of TiO/RGO are 72 s and 99 s, respectively, while those of α-FeO/RGO are 48 s and 54 s. Both sensors demonstrate good repeatability and stability. These findings suggest that SMO/RGO nanocomposites are promising materials for the development of low-cost, high-sensitivity, and stable humidity sensors.
本研究在室温下研究了两种半导体金属氧化物(SMO)-还原氧化石墨烯(RGO)纳米复合材料:TiO/RGO和α-FeO/RGO的湿度传感特性。两种纳米复合材料均通过水热法合成,并涂覆在印刷电路板(PCB)叉指电极上以构建湿度传感器。使用场发射扫描电子显微镜(FESEM)和X射线衍射(XRD)对材料的表面形态和晶体结构进行了表征。在11%RH至97%RH的湿度范围内对传感器进行测试,并在1Hz至1MHz的频率范围内测量阻抗。结果表明,TiO/RGO和α-FeO/RGO在室温下均表现出良好的湿度传感性能。TiO/RGO的灵敏度和湿度滞后分别为12.2MΩ/%RH和3.811%RH,而α-FeO/RGO的灵敏度和湿度滞后分别为0.826MΩ/%RH和8.229%RH。TiO/RGO的响应时间和恢复时间分别为72秒和99秒,而α-FeO/RGO的响应时间和恢复时间分别为48秒和54秒。两种传感器均表现出良好的重复性和稳定性。这些发现表明,SMO/RGO纳米复合材料是开发低成本、高灵敏度和稳定湿度传感器的有前途的材料。