Mostafa A S, Kassab M M, Radwan M M, Al Kaisy Ahmed M, Abdel-Latif M A
Department of Engineering Mathematics and Physics, Faculty of Engineering, Fayoum University, 63514, Fayoum, Egypt.
Department of Engineering Mathematics and Physics, Faculty of Engineering, Fayoum University, 63514, Fayoum, Egypt; Department of Basic & Medical Sciences, Faculty of Dentistry, Al Ryada University for Science & Technology, Egypt; Department of Basic & Medical Sciences, Faculty of Physical Therapy, Al Ryada University for Science & Technology, Egypt.
Appl Radiat Isot. 2025 Jun;220:111742. doi: 10.1016/j.apradiso.2025.111742. Epub 2025 Feb 18.
A novel Zinc-Tellurite borosilicate (ZTBS) glass system was successfully synthesized via the melt quench process. Its chemical composition is represented by the formula (44SiO-25BO-18NaO-6CaO-1ZrO-(6-x)ZnO-xTeO), and its weight fraction (x = 0, 2, 4, 6 wt%). The shielding properties, there is perfect agreement between the results of the theoretical calculation of the mass attenuation coefficient using the Phy-X/PSD and the compatible values derived from the WinXCom databases. Further, several photon shielding parameters were computed in the 15 keV-15 MeV energy range, including the mass attenuation coefficient (MAC), half value layer (HVL), mean free path (MFP), exposure buildup factor (EBF), and effective atomic number (Z). The preferred sample for gamma ray shielding is the sample with the highest TeO concentration (ZTBS3), according to the results. ZTBS3 glass samples have greater MAC and HVL values than other published borosilicate glasses at 662.61 k eV photon energy which reaches 0.07626 cm/g and 3.429 cm respectively. Also, LAC values is higher in the sample with the largest concentration of TeO. Furthermore, the computed HVL and MFP were lower than those of regular concrete. The shielding results indicate that the newly developed transparent ZTBS glasses compositions that are lightweight and have good shielding properties that may be suitable in shielding applications. Depending on the application, the ratio of TeO additive should be balanced between improved shielding and glass stability features.
通过熔体淬火工艺成功合成了一种新型锌碲硼硅酸盐(ZTBS)玻璃体系。其化学组成由化学式(44SiO-25BO-18NaO-6CaO-1ZrO-(6-x)ZnO-xTeO)表示,其重量分数为(x = 0、2、4、6 wt%)。在屏蔽性能方面,使用Phy-X/PSD进行的质量衰减系数理论计算结果与从WinXCom数据库得出的兼容值之间存在完美的一致性。此外,在15 keV - 15 MeV能量范围内计算了几个光子屏蔽参数,包括质量衰减系数(MAC)、半值层(HVL)、平均自由程(MFP)、照射量积累因子(EBF)和有效原子序数(Z)。结果表明,对于伽马射线屏蔽而言,最佳样品是TeO浓度最高的样品(ZTBS3)。在662.61 keV光子能量下,ZTBS3玻璃样品的MAC和HVL值分别达到0.07626 cm/g和3.429 cm,高于其他已发表的硼硅酸盐玻璃。此外,TeO浓度最高的样品中的LAC值也更高。而且,计算得到的HVL和MFP低于普通混凝土。屏蔽结果表明,新开发的透明ZTBS玻璃组合物重量轻且具有良好的屏蔽性能,可能适用于屏蔽应用。根据应用情况,TeO添加剂的比例应在提高屏蔽性能和玻璃稳定性之间取得平衡。