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生物质衍生碳点:合成、改性及其在电池中的应用。

Biomass-derived carbon dots: synthesis, modification and application in batteries.

作者信息

Cai Dongyang, Zhong Xue, Xu Laiqiang, Xiong Yu, Deng Wentao, Zou Guoqiang, Hou Hongshuai, Ji Xiaobo

机构信息

College of Chemistry and Chemical Engineering, Central South University Changsha 410083 China

Key Laboratory of Renewable Energy Electric-Technology of Hunan Province, School of Energy and Power Engineering, Changsha University of Science and Technology Changsha 410114 China

出版信息

Chem Sci. 2025 Feb 25;16(12):4937-4970. doi: 10.1039/d4sc08659g. eCollection 2025 Mar 19.

Abstract

Biomass-derived carbon dots (BCDs) have attracted considerable attention for their promising attributes, including low toxicity, excellent solubility, biocompatibility, and eco-friendliness. Their rich surface chemistry and impressive photoluminescent properties have sparked widespread research interest, particularly in areas such as sensing and biomedicine. However, the potential applications of BCDs in the energy sector, especially in electrochemical energy storage batteries, have received scant review focus. This article systematically consolidates the selection of carbon sources, synthesis methods, modification strategies, and the corresponding characterization techniques for BCDs. Application strategies in energy storage batteries are explored, with the underlying connection between the role of BCDs in batteries and their structural properties being analyzed, providing comprehensive insights from synthesis and characterization to application. Furthermore, a preliminary discussion is initiated on the current limitations in material regulation and design within research, and potential avenues for enhancement are proposed.

摘要

生物质衍生的碳点(BCDs)因其具有低毒性、出色的溶解性、生物相容性和环境友好性等有前景的特性而备受关注。它们丰富的表面化学性质和令人印象深刻的光致发光特性引发了广泛的研究兴趣,特别是在传感和生物医学等领域。然而,BCDs在能源领域的潜在应用,尤其是在电化学储能电池方面,却很少受到综述关注。本文系统地总结了BCDs的碳源选择、合成方法、改性策略以及相应的表征技术。探讨了其在储能电池中的应用策略,分析了BCDs在电池中的作用与其结构性质之间的潜在联系,从合成、表征到应用提供了全面的见解。此外,还对当前研究中材料调控和设计的局限性进行了初步讨论,并提出了潜在的改进途径。

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