Contact-electro-catalysis (CEC) has emerged as a promising catalytic methodology, integrating principles from solid-liquid triboelectric nanogenerators (SL-TENGs) into catalysis. Unlike conventional approaches, CEC harnesses various forms of mechanical energy, including wind and water, along with other renewable sources, enabling reactions under natural conditions without reliance on specific energy inputs like light or electricity. This review presents the basic principles of CEC and discusses its applications, including the degradation of organic molecules, synthesis of chemical substances, and reduction of metals. Furthermore, it explores methods to improve the catalytic efficiency of CEC by optimizing catalytic conditions, the structure of catalyst materials, and the start-up mode. The concluding section offers insights into future prospects and potential applications of CEC, highlighting its role in advancing sustainable catalytic technologies.