Zverev Sergei, Savraeva Daria, Ignatova Yulia, Aristova Victoria, Martynov Leonid, Sakharov Konstantin, Dubinich Valeriya, Andreev Sergei
Disinfectology Institute of F.F. Erisman FSCH of Rospotrebnadzor, 18 Nauchny Drive, Moscow 117246, Russia.
MIREA-Russian Technological University (M.V. Lomonosov Institute of Fine Chemical Technologies), 86 Vernadsky Prospekt, Moscow 119571, Russia.
Molecules. 2025 Feb 24;30(5):1036. doi: 10.3390/molecules30051036.
In this study, electrically conductive polymer composites based on repellent ,-diethyl-3-methylbenzamide with concentrations ranging from 6 to 30 wt% were developed. The electrical resistivity of repellent composites, as determined by electrochemical impedance spectra, ranges from 150 to 171 Ohm, which allows such materials to be used when a low voltage is applied. The study of the rheological properties of the obtained repellent composites and the analysis of the TGA curves demonstrated that the dynamic viscosity of the materials has a significant effect on the thermal diffusion of the repellent. The study of the thermal diffusion of ,-diethyl-3-methylbenzamide demonstrated that a higher yield of repellent (up to 36.4 × 10 mol) is achieved when the material is applied in the form with the shortest conductor length of 14 mm. The graphs showing the relationship between the electrical flux and the concentration of ,-diethyl-3-methylbenzamide, which was calculated via the Peltier and Thompson equations, show that, according to Onsager's theory, the total flux of the substance is highest when a voltage is applied to the material with the shortest conductor length. Thus, the developed repellent composite is a promising material for protection against blood-sucking insects.
在本研究中,开发了基于驱蚊剂N,N-二乙基-3-甲基苯甲酰胺、浓度范围为6至30 wt%的导电聚合物复合材料。通过电化学阻抗谱测定,驱蚊复合材料的电阻率在150至171欧姆之间,这使得此类材料在施加低电压时能够被使用。对所得驱蚊复合材料的流变性能研究以及热重分析(TGA)曲线分析表明,材料的动态粘度对驱蚊剂的热扩散有显著影响。对N,N-二乙基-3-甲基苯甲酰胺热扩散的研究表明,当材料以最短导体长度为14毫米的形式应用时,驱蚊剂的产率更高(高达36.4×10⁻³摩尔)。通过珀尔帖和汤普森方程计算得出的显示电通量与N,N-二乙基-3-甲基苯甲酰胺浓度之间关系的图表表明,根据昂萨格理论,当对最短导体长度的材料施加电压时,物质的总通量最高。因此,所开发的驱蚊复合材料是一种有前景的防吸血昆虫材料。