Jangir Tarun, Nipate Dhananjay S, Rangan Krishnan, Kumar Anil
Department of Chemistry, Birla Institute of Technology and Science, Pilani, Pilani Campus, Vidya Vihar, Pilani, Rajasthan, 333031, India.
Department of Chemistry, Birla Institute of Technology and Science, Pilani, Hyderabad Campus, Jawahar Nagar, Kapra Mandal, Medchal District, Telangana 500078, India.
Chem Commun (Camb). 2025 Apr 11;61(31):5762-5765. doi: 10.1039/d5cc00318k.
A ruthenium(II)-catalyzed direct oxidative (4+3) C-H/C-H annulation of 2-aryl-4-pyrido[1,2-]pyrimidin-4-ones with allyl alcohol has been described. The developed method yielded the corresponding annulated products in moderate to good yields. In addition, based on the control experimental results, a possible reaction mechanism has been proposed for the (4+3) C-H/C-H annulation reaction.
已报道了一种钌（II）催化的2-芳基-4-吡啶并[1,2 -]嘧啶-4-酮与烯丙醇的直接氧化（4 + 3）C-H/C-H环化反应。所开发的方法以中等至良好的产率得到相应的环化产物。此外，基于对照实验结果，提出了（4 + 3）C-H/C-H环化反应可能的反应机理。
