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生物质燃烧后过程中气态和细颗粒污染物的捕集。

Capture of gaseous and fine particulate pollutants emitted in the biomass post-combustion process.

作者信息

Costa Maria Angélica Martins, de Souza Alexandre Jorge Duarte, Mello Bruna Sampaio, de Oliveira Eliza Almeida, Oliveira Lucas Freitas, Albini Geisa, Sarti Arnaldo, Dussán Kelly Johana

机构信息

Department of Chemical Engineering, Institute of Chemistry, São Paulo State University, UNESP, Brazil. Av. Prof. Francisco Degni, 55 - Jardim Quitandinha, Araraquara, São Paulo, CEP 14800-900, Brazil.

Department of Industrial Timber Engineering, Universidade Estadual Paulista, UNESP, Campus of Itapeva, Brazil, São Paulo State University-UNESP, Itapeva, São Paulo, Brazil.

出版信息

Environ Sci Pollut Res Int. 2025 Mar 25. doi: 10.1007/s11356-025-36242-5.

Abstract

PURPOSE

Emissions of gaseous pollutants, particularly carbon dioxide (CO) and particulate matter, are increasing, primarily due to anthropogenic combustion of conventional fossil fuels. These emissions drive global warming and climate change, contributing to significant environmental and health impacts. This scenario highlights the urgent need for cleaner energy solutions, prompting industries and power plants to transition rapidly to sustainable sources such as biomass. While biomass combustion is carbon neutral regarding atmospheric CO, it still generates particulate matter that must be controlled. Integrated strategies for CO capture, sequestration, storage, and utilization, along with effective particulate capture, are essential for reducing greenhouse gas emissions and minimizing health risks.

AIM

This study primarily evaluates laboratory- and pilot-scale technologies for mitigating industrial CO and fine particulate matter emissions from biomass combustion.

METHODS

Emissions of gaseous and particulate pollutants were evaluated using a pilot burner. Initial CO capture tests were performed in a laboratory absorption column, followed by biomass combustion evaluations using a Venturi scrubber for gas capture and particulate removal.

RESULTS

The results indicated low CO capture efficiencies without chemical reactions. When a NaOH solution was used for chemical absorption at flow rates of 1.4, 1.8, and 2.0 L/min, capture efficiencies improved to 10.3, 10.4, and 17.24%, respectively. The Venturi scrubber effectively captured particulate matter but was less effective for CO, although it performed well in capturing CO and NO gases.

CONCLUSION

Emissions of gaseous pollutants and PM were significantly high during the burning of biomass, such as sugar cane bagasse. The results showed high capture efficiencies for PM below 1.0 μm, reaching values above 80%. Advancements in capture technologies can help industries transition to sustainable practices, addressing both climate goals and air quality standards.

摘要

目的

气态污染物,特别是二氧化碳(CO)和颗粒物的排放正在增加,这主要归因于传统化石燃料的人为燃烧。这些排放推动了全球变暖和气候变化,对环境和健康造成了重大影响。这种情况凸显了对清洁能源解决方案的迫切需求,促使工业和发电厂迅速转向生物质等可持续能源。虽然生物质燃烧在大气CO方面是碳中性的,但它仍然会产生必须加以控制的颗粒物。CO捕获、封存、储存和利用的综合策略,以及有效的颗粒物捕获,对于减少温室气体排放和将健康风险降至最低至关重要。

目标

本研究主要评估用于减轻生物质燃烧产生的工业CO和细颗粒物排放的实验室规模和中试规模技术。

方法

使用中试燃烧器评估气态和颗粒物污染物的排放。最初的CO捕获测试在实验室吸收塔中进行,随后使用文丘里洗涤器进行气体捕获和颗粒物去除,对生物质燃烧进行评估。

结果

结果表明,在没有化学反应的情况下,CO捕获效率较低。当使用NaOH溶液以1.4、1.8和2.0 L/min的流速进行化学吸收时,捕获效率分别提高到10.3%、10.4%和17.24%。文丘里洗涤器有效地捕获了颗粒物,但对CO的效果较差,尽管它在捕获CO和NO气体方面表现良好。

结论

在生物质(如甘蔗渣)燃烧过程中,气态污染物和PM的排放显著较高。结果表明,对于粒径小于1.0μm的PM,捕获效率较高,达到80%以上。捕获技术的进步可以帮助工业转向可持续做法,实现气候目标和空气质量标准。

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