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用于电化学应用中碳纳米管和石墨烯基底的含金属颗粒的可再生糖类衍生多孔碳泡沫材料。

Renewable saccharide-derived porous carbon foams with metal particles for CNT and graphene substrates in electrochemical applications.

作者信息

Ma Yi, Coley William, Shang Ruoxu, Villalobos Fabian, Pena Pedro, Patalano Andrew, Jauregui Evan, Roskopf Nicholas, Ozkan Mihrimah, Ozkan Cengiz S

机构信息

Department of Mechanical Engineering, University of California, Riverside, Riverside, CA 92521 USA.

Materials Science and Engineering Program, University of California, Riverside, Riverside, CA 92521 USA.

出版信息

iScience. 2025 Feb 17;28(3):112050. doi: 10.1016/j.isci.2025.112050. eCollection 2025 Mar 21.

Abstract

Harnessing the potential of renewable saccharides, porous carbon foams embedded with metal nanoparticles have been innovatively synthesized, pushing the boundaries of electrochemical applications. By embedding metal nanoparticles in carbon foams derived from saccharides and metal salts, substrates for the growth of multi-walled carbon nanotubes (MWCNTs) and multi-layer graphene through chemical vapor deposition (CVD) are created. The influence of varying saccharide-to-metal precursor ratios on the morphology of these nano-structured carbons is examined. The diameters of carbon nanotubes formed at different saccharide to nickel (Ni) ratios are compared, with corroborative insights from X-ray diffraction (XRD) and Raman spectroscopy. Substituting cobalt (Co) salts for Ni precursors reveals notable differences in carbon morphologies. The resulting carbon nanotube-carbon foam composites exhibit remarkable properties, enabling the creation of hierarchical carbon foams. Furthermore, their potential as carbon electrodes for electrochemical double-layer capacitors (EDLCs) is evaluated, highlighting their promise in cutting-edge electrochemical applications.

摘要

利用可再生糖类的潜力,创新性地合成了嵌入金属纳米颗粒的多孔碳泡沫,拓展了电化学应用的边界。通过将金属纳米颗粒嵌入由糖类和金属盐衍生而来的碳泡沫中,制备出了用于通过化学气相沉积(CVD)生长多壁碳纳米管(MWCNT)和多层石墨烯的基底。研究了不同糖类与金属前驱体比例对这些纳米结构碳形态的影响。比较了在不同糖类与镍(Ni)比例下形成的碳纳米管的直径,并结合X射线衍射(XRD)和拉曼光谱的佐证见解进行分析。用钴(Co)盐替代镍前驱体,发现碳形态存在显著差异。所得的碳纳米管-碳泡沫复合材料展现出卓越性能,能够制备出分级碳泡沫。此外,还评估了它们作为电化学双层电容器(EDLC)碳电极的潜力,突出了其在前沿电化学应用中的前景。

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